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明胶在低压缩性粉质黏土混合物可持续稳定中的应用:岩土工程特性及碳排放考量

Application of Gelatin for Sustainable Stabilization of Low-Compressible Silt-Clay Mixtures: Geotechnical Behavior and Carbon Emission Considerations.

作者信息

Sujatha Evangelin Ramani, Pratheeba Veera Ragavan, Baldovino Jair De Jesus Arrieta, Nunez de la Rosa Yamid E

机构信息

Centre for Advanced Research in Environment, School of Civil Engineering, SASTRA Deemed University, Thanjavur 613401, India.

Applied Geotechnical Research Group, Civil Engineering Program, Universidad de Cartagena, Cartegena de Indias 130015, Colombia.

出版信息

Polymers (Basel). 2025 Jul 17;17(14):1954. doi: 10.3390/polym17141954.

Abstract

Biopolymers, owing to their environmentally friendly and sustainable characteristics, have become a promising alternative for soil stabilization in geotechnical engineering. The application of protein-based biopolymers as binders for soil stabilization is less prevalent in geotechnical engineering compared to polysaccharide-based biopolymers. This study explores the potential of gelatin, a protein-based biopolymer derived from animal collagen, for stabilizing silty sand and improving its geotechnical properties. Gelatin was mixed into the soil at concentrations ranging from 0.25% to 2% of the dry weight of soil, and its effects on various soil characteristics were evaluated. The tests conducted include liquid limit, plastic limit, compaction behavior, and unconfined compressive strength (UCS); the addition of 1% gelatin led to an approximate 1.69 times increase in the strength of the unamended soil. After 28 days of curing, the UCS improved by approximately 5.03 times compared to the untreated soil, and the treated soil exhibited increased resistance to deformation under load. Microstructural analysis using scanning electron microscopy (SEM) revealed that gelatin facilitated the formation of a cohesive matrix, enhancing particle bonding and reducing void spaces within the soil. Carbon footprint analysis (CFA) conducted on an isolated footing stabilized with gelatin showed that the carbon emissions were reduced by 99.8% and 99% compared to traditional stabilizers such as lime and cement. Additionally, the interaction between the biopolymer and the fine-grained soil is distinctly evident in the FTIR and XRD analysis through hydrogen bonding and the formation of cementitious compounds.

摘要

生物聚合物因其环保和可持续的特性,已成为岩土工程中土壤稳定化的一种有前景的替代材料。与基于多糖的生物聚合物相比,基于蛋白质的生物聚合物作为土壤稳定化粘结剂在岩土工程中的应用较少。本研究探讨了明胶(一种源自动物胶原蛋白的基于蛋白质的生物聚合物)对粉砂进行稳定化处理并改善其岩土工程性质的潜力。将明胶以土壤干重的0.25%至2%的浓度混入土壤中,并评估其对各种土壤特性的影响。进行的试验包括液限、塑限、压实特性和无侧限抗压强度(UCS);添加1%的明胶使未改良土壤的强度提高了约1.69倍。养护28天后,与未处理土壤相比,无侧限抗压强度提高了约5.03倍,且处理后的土壤在荷载作用下表现出更高的抗变形能力。使用扫描电子显微镜(SEM)进行的微观结构分析表明,明胶促进了粘性基质的形成,增强了颗粒间的粘结力并减少了土壤中的孔隙空间。对用明胶稳定化的独立基础进行的碳足迹分析(CFA)表明,与石灰和水泥等传统稳定剂相比,碳排放减少了99.8%和99%。此外,通过傅里叶变换红外光谱(FTIR)和X射线衍射(XRD)分析可知,生物聚合物与细粒土之间通过氢键和胶凝化合物的形成产生的相互作用十分明显。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c258/12298347/79f507e79996/polymers-17-01954-g001.jpg

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