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Preparation of Barium Europium Phosphate and Its Performance in Acrylic Resin Anti-Corrosion Coating.

作者信息

Deng Xuying, Wang Jihu, Wen Shaoguo, Zhao Jiale, Zhang Xue, Zhao Yicheng, Deng Zhiying

机构信息

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China.

出版信息

Polymers (Basel). 2025 Jul 17;17(14):1966. doi: 10.3390/polym17141966.

DOI:10.3390/polym17141966
PMID:40732845
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12300441/
Abstract

Acrylic resin is a polymer with strong crosslinking density and strength, and it is commonly used as a matrix in water-based coatings. Barium europium phosphate (BaEu(PO)) is a novel functional filler that is expected to provide anti-corrosive effects to coatings. In this study, BaEu(PO) was prepared by the high-temperature solid-phase method and applied to acrylic anti-corrosion coatings. The influence of the molar ratio of reactants on BaEu(PO) purity was studied. The anti-corrosion performance of the coating was investigated. It was found that, when BaCO:EuO:(NH)HPO = 3:0.5:3 and the reaction was carried out at 950 °C for 1000 min, high-purity BaEu(PO) can be obtained, according to XRD and EDS tests. SEM shows that BaEu(PO) has good crystal morphology and a porous morphology. TEM revealed that its structure was intact. When BaEu(PO) was added to a relative resin content of 5 wt%, the anti-corrosion performance of the coating was the best after 168 h, with the lowest Tafel current density of 9.616 μA/cm and the largest capacitance arc curvature radius. The salt spray resistance test showed that the corrosion resistance of the 5 wt% BaEu(PO) coating was also the best, which is consistent with the results of the electrochemical test. BaEu(PO) as a pigment and filler can effectively improve the anti-corrosion performance of water-based industrial coatings.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/54e118a4649c/polymers-17-01966-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/9f956c230629/polymers-17-01966-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/32510f6db086/polymers-17-01966-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/858420c746d2/polymers-17-01966-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/dcfedcfffcae/polymers-17-01966-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/a0cd47547661/polymers-17-01966-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/88e3bdbe8f22/polymers-17-01966-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/962aa0a26558/polymers-17-01966-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/3a0bde41e341/polymers-17-01966-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/6e61a08e0d2d/polymers-17-01966-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/4cb6b5c0873a/polymers-17-01966-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/a6de0b7e4cad/polymers-17-01966-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/ac1ab55d1e4c/polymers-17-01966-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/54e118a4649c/polymers-17-01966-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/9f956c230629/polymers-17-01966-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/32510f6db086/polymers-17-01966-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/858420c746d2/polymers-17-01966-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/dcfedcfffcae/polymers-17-01966-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/a0cd47547661/polymers-17-01966-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/88e3bdbe8f22/polymers-17-01966-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/962aa0a26558/polymers-17-01966-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/3a0bde41e341/polymers-17-01966-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/6e61a08e0d2d/polymers-17-01966-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/4cb6b5c0873a/polymers-17-01966-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/a6de0b7e4cad/polymers-17-01966-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/ac1ab55d1e4c/polymers-17-01966-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/340c/12300441/54e118a4649c/polymers-17-01966-g013.jpg

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J Colloid Interface Sci. 2021 Jul 15;594:604-620. doi: 10.1016/j.jcis.2021.03.048. Epub 2021 Mar 15.
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