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具有增强强度和耐磨性的工业废料高性能聚四氟乙烯复合材料。

High-performance PTFE composites from industrial scrap with enhanced strength and wear resistance.

作者信息

Kamal Ahmed, Mosleh Ahmed O, Gaafer Ahmed, Youness Rasha A, Taha Mohammed A

机构信息

Mechanical Engineering Department, Shoubra Faculty of Engineering, Benha University, 108 Shoubra St, Banha, Egypt.

Spectroscopy Department, National Research Centre, El Buhouth St, Dokki, Giza, 12622, Egypt.

出版信息

Sci Rep. 2025 Aug 4;15(1):28445. doi: 10.1038/s41598-025-13643-7.

Abstract

Due to the high cost of raw materials, this work aims to utilize polytetrafluoroethylene (PTFE) scrap generated from industrial waste to produce composites possessing superior properties for potential use in various industrial applications. In this respect, PTFE-based composites reinforced with mono- and hybrid granite and boron carbide (BC) nanoparticles are produced using powder metallurgy (PM) technology. The sintered composites' physical, mechanical, tribological, and thermal properties and the phase composition and microstructure were investigated using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) techniques, respectively. The results indicated that the phase composition of the prepared composites did not change. Adding granite and/or BC to the PTFE base increased the bulk density and the total porosity, while the relative density decreased. In addition, after adding 5 vol% granite/5 vol% BC (PTFE6 sample), there was a clear improvement in mechanical properties, including microhardness, ultimate, and Young's modulus, reaching 123.29%, 91.33%, and 74.17% compared with the unreinforced sample (PTFE0). Moreover, there was a noticeable improvement in the wear rate, fraction coefficient, and thermal expansion coefficient (CTE) value for the same sample, which decreased by approximately 37.17%, 36.50%, and 61.64%.

摘要

由于原材料成本高昂,本研究旨在利用工业废料产生的聚四氟乙烯(PTFE)废料来制备具有优异性能的复合材料,以用于各种工业应用。在这方面,采用粉末冶金(PM)技术制备了以单花岗岩和硼化碳(BC)纳米颗粒增强的PTFE基复合材料。分别使用X射线衍射(XRD)和场发射扫描电子显微镜(FESEM)技术研究了烧结复合材料的物理、机械、摩擦学和热性能以及相组成和微观结构。结果表明,所制备复合材料的相组成没有变化。向PTFE基体中添加花岗岩和/或BC会增加体积密度和总孔隙率,而相对密度会降低。此外,添加5体积%花岗岩/5体积%BC(PTFE6样品)后,包括显微硬度、极限强度和杨氏模量在内的机械性能有明显改善,与未增强样品(PTFE0)相比,分别提高了123.29%、91.33%和74.17%。此外,同一样品的磨损率、摩擦系数和热膨胀系数(CTE)值也有显著改善,分别降低了约37.17%、36.50%和61.64%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9da3/12322259/5b19c74c0952/41598_2025_13643_Fig2_HTML.jpg

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