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双酚A的声化学降解:一种协同双频超声方法。

Sonochemical degradation of bisphenol A: A synergistic dual-frequency ultrasound approach.

作者信息

Fletcher Shaun, Yusuf Lukman A, Ertekin Zeliha, Symes Mark D

机构信息

School of Chemistry, University of Glasgow, Glasgow G12 8QQ, United Kingdom.

School of Chemistry, University of Glasgow, Glasgow G12 8QQ, United Kingdom.

出版信息

Ultrason Sonochem. 2025 Jul 30;120:107488. doi: 10.1016/j.ultsonch.2025.107488.

DOI:10.1016/j.ultsonch.2025.107488
PMID:40763557
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12341535/
Abstract

The persistence of bisphenol A in the environment poses significant ecological hazards. Traditional treatment methods often fall short in removing micropollutants such as bisphenol A from wastewater. The use of ultrasound in water treatment has the potential to induce powerful oxidative degradation of micropollutants while dispensing with the need for chemical intervention. Herein, we show a novel approach for the sonochemical degradation of bisphenol A using dual frequency ultrasound. The synergistic effects of using two distinct ultrasonic frequencies (20 kHz, with the addition of either 37 kHz or 80 kHz) were investigated in the context of bisphenol A removal. The method was shown to substantially increase the rate of degradation compared to single frequency treatment, achieving a 94% removal of bisphenol A under optimised conditions. The high extent of chemical oxygen demand removal and the absence of a requirement for chemical additives demonstrates the promise of this method as a green alternative for water treatment.

摘要

双酚A在环境中的持久性带来了重大的生态危害。传统处理方法在从废水中去除双酚A等微污染物方面往往效果不佳。在水处理中使用超声波有潜力引发微污染物的强力氧化降解,同时无需化学干预。在此,我们展示了一种使用双频超声对双酚A进行声化学降解的新方法。在双酚A去除的背景下,研究了使用两种不同超声频率(20kHz,添加37kHz或80kHz)的协同效应。结果表明,与单频处理相比,该方法显著提高了降解速率,在优化条件下实现了94%的双酚A去除率。高化学需氧量去除率以及无需化学添加剂表明了该方法作为一种绿色水处理替代方法的前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/a69221103b6c/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/0d6ca99b7fed/ga1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/a62ff70ac2e1/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/99d7735b2b1f/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/cbc115cd9a69/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/a69221103b6c/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/0d6ca99b7fed/ga1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/a62ff70ac2e1/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/99d7735b2b1f/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/cbc115cd9a69/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef8c/12341535/a69221103b6c/gr4.jpg

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本文引用的文献

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Advanced technologies for the determination of quantitative structure-activity relationships and degradation efficiency of micropollutants and their removal in water - A review.高级技术用于确定微量污染物的定量结构-活性关系和降解效率及其在水中的去除 - 综述。
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Impact of sonication power on the degradation of paracetamol under single- and dual-frequency ultrasound.
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A fundamental study on the degradation of paracetamol under single- and dual-frequency ultrasound.关于单频和双频超声下对扑热息痛降解的基础研究。
Ultrason Sonochem. 2023 Mar;94:106320. doi: 10.1016/j.ultsonch.2023.106320. Epub 2023 Feb 6.
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An alternative technique for determining the number density of acoustic cavitation bubbles in sonochemical reactors.一种用于确定声化学反应器中声空化气泡数密度的替代技术。
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