极化带电卟啉的离子对组装体
Ion-Pairing Assemblies of Polarized Charged Porphyrin.
作者信息
Kitayama Ryo, Haketa Yohei, Maruyama Yuto, Fujita Masaki, Tanaka Hiroki, Horita Hiroki, Maeda Hiromitsu
机构信息
Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu, 525-8577, Japan.
出版信息
Chemistry. 2025 Sep 1;31(49):e02225. doi: 10.1002/chem.202502225. Epub 2025 Aug 7.
A porphyrin Au complex comprising 5,10-penatafluorophenyl units was synthesized as a dipolar π-electronic cation. The π-electronic cation was combined with anions, including a bulky borate anion and planar π-electronic anions. The dipolar π-electronic cation formed crystal-state ion-pairing assemblies based on antiparallel stacking structures, which were stabilized by interionic dipole-dipole interactions.
一种包含5,10-五氟苯基单元的卟啉金配合物被合成为一种偶极π电子阳离子。该π电子阳离子与包括大体积硼酸根阴离子和平面π电子阴离子在内的阴离子相结合。偶极π电子阳离子基于反平行堆积结构形成晶体态离子对组装体，这些组装体通过离子间偶极-偶极相互作用得以稳定。
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