Zhuang Ruobin, He Jianfeng, Lin Haoyang, Luo Huijian, Lin Leqing, Wang Lihao, Liu Bin, Zhu Wenguo, Zhong Yongchun, Yu Jianhui, Sigrist Markus, Zheng Huadan
International Cooperation Joint Laboratory for Optoelectronic Hybrid Integrated Circuits, Jinan University, Guangzhou 510632, China.
Guangdong-Hong Kong-Macao Joint Laboratory for Intelligent Micro-Nano Optoelectronic Technology, Foshan University, Foshan 528000, China.
Photoacoustics. 2025 Jul 23;45:100752. doi: 10.1016/j.pacs.2025.100752. eCollection 2025 Oct.
Accurate and rapid detection of hydrogen and hydrocarbons is critical for safety and efficiency in modern energy, industrial, and environmental systems. However, selective and simultaneous quantification of these species remains a significant technical challenge. Here, we introduce conductance-photoacoustic spectroscopy (ConPAS), an integrated sensing approach that combines conductance-based resonance modulation with quartz-enhanced photoacoustic spectroscopy in a single device. By bridging a quartz tuning fork (QTF) with a catalytic platinum microwire, ConPAS enables concurrent extraction of hydrogen and hydrocarbon concentrations from a unified electrical signal: hydrogen is quantified by frequency analysis, while hydrocarbon content is determined by amplitude analysis simultaneously. Experiments demonstrate minimum detection limits of 0.69 % for hydrogen, 40.26 ppm for propane, and 133.7 ppm for methane, with millisecond response time and excellent linearity (R² > 0.99). The modular architecture allows flexible adaptation to other analytes via material substitution, offering a scalable and versatile solution for simultaneous, multi-component gas sensing. This work establishes ConPAS as a powerful, calibration-compatible platform for integrated gas analysis in hydrogen-enriched environments, with broad implications for safety monitoring, process control, and advanced energy applications.
准确快速地检测氢气和碳氢化合物对于现代能源、工业和环境系统的安全与效率至关重要。然而,对这些物质进行选择性和同时定量分析仍然是一项重大的技术挑战。在此,我们介绍了电导光声光谱法(ConPAS),这是一种集成传感方法,它将基于电导的共振调制与石英增强光声光谱法集成在一个单一设备中。通过将石英音叉(QTF)与催化铂微丝相连,ConPAS能够从统一的电信号中同时提取氢气和碳氢化合物的浓度:氢气通过频率分析进行定量,而碳氢化合物含量则通过幅度分析同时确定。实验表明,氢气的最低检测限为0.69%,丙烷为40.26 ppm,甲烷为133.7 ppm,响应时间为毫秒级,线性度极佳(R²>0.99)。模块化架构允许通过材料替换灵活适应其他分析物,为同时进行多组分气体传感提供了一种可扩展且通用的解决方案。这项工作将ConPAS确立为一个强大的、与校准兼容的平台,用于在富氢环境中进行集成气体分析,对安全监测、过程控制和先进能源应用具有广泛的意义。