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FeAlCrNiV共晶复合浓缩合金的结构与力学性能

The Structure and Mechanical Properties of FeAlCrNiV Eutectic Complex Concentrated Alloy.

作者信息

Pešička Josef, Veselý Jozef, Král Robert, Daniš Stanislav, Minárik Peter, Jača Eliška, Šmilauerová Jana

机构信息

Department of Physics of Materials, Charles University, 12116 Prague, Czech Republic.

Department of Condensed Matter Physics, Charles University, 12116 Prague, Czech Republic.

出版信息

Materials (Basel). 2025 Aug 5;18(15):3675. doi: 10.3390/ma18153675.

DOI:10.3390/ma18153675
PMID:40805556
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12348156/
Abstract

In this work, the microstructure and mechanical properties of the FeAlCrNiV complex concentrated alloy (CCA) were studied in the as-cast and annealed states. The material was annealed at 800 °C for 16 days to test microstructure stability and phase evolution. It was found that the microstructure does not differ in the two investigated states, and the results of differential scanning calorimetry and dilatometry showed that there is almost no difference in the thermal response between the as-cast and annealed states. Both investigated states exhibit eutectic structure with bcc solid solution and ordered phase with B2 symmetry. In a single grain, several regions with B2 laths in the bcc matrix were observed. Inside the B2 laths and in the bcc matrix, bcc spheres and B2 spheres were observed, respectively. All three features-laths, matrix and spheres-are fully crystallographically coherent. Nevertheless, in the adjacent region in the grain, the crystal structure of the matrix, laths and sphere changed to the other structure, i.e., the characteristics of the microstructure feature with B2 symmetry changed to bcc, and vice versa. Compression deformation tests were performed for various temperatures from room temperature to 800 °C. The results showed that the material exhibits exceptional yield stress values, especially at high temperatures (820 MPa/800 °C), and excellent plasticity (25%).

摘要

在本工作中,研究了铸态和退火态FeAlCrNiV复杂集中合金(CCA)的微观结构和力学性能。将材料在800℃退火16天,以测试微观结构稳定性和相演变。结果发现,在两种研究状态下微观结构并无差异,差示扫描量热法和膨胀法的结果表明,铸态和退火态之间的热响应几乎没有差异。两种研究状态均呈现出具有体心立方(bcc)固溶体的共晶结构和具有B2对称性的有序相。在单个晶粒中,观察到在bcc基体中有几个具有B2板条的区域。在B2板条内部和bcc基体中,分别观察到bcc球和B2球。板条、基体和球这三个特征在晶体学上完全连贯。然而,在晶粒中的相邻区域,基体、板条和球的晶体结构转变为另一种结构,即具有B2对称性的微观结构特征转变为bcc,反之亦然。对从室温到800℃的不同温度进行了压缩变形试验。结果表明,该材料表现出异常的屈服应力值,尤其是在高温下(820MPa/800℃),并且具有优异的塑性(25%)。

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本文引用的文献

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A promising new class of high-temperature alloys: eutectic high-entropy alloys.一类有前景的新型高温合金:共晶高熵合金。
Sci Rep. 2014 Aug 27;4:6200. doi: 10.1038/srep06200.