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利用啤酒麦芽渣和农作物的马铃薯残渣开发可生物降解泡沫托盘。

Development of Biodegradable Foam Trays from Brewer's Malt Bagasse and Potato Residues from Agricultural Crops.

作者信息

Vásquez-Bacilio Evelyn F, Mejia-Llontop Cesar I, Tirado-Rodríguez Carlos E, Arévalo-Oliva María de Fátima, Hurtado-Soria Beetthssy Z, Villanueva Eudes, Rodriguez Gilbert, Tapia-Blácido Delia Rita, Aguirre Elza

机构信息

Escuela de Posgrado, Universidad Nacional del Santa, Av. Universitaria s/n, Nuevo Chimbote 02712, Ancash, Peru.

Laboratorio de Microbiología y Toxicología de Productos Agroindustriales, Universidad Nacional del Santa (UNS), Urb. Av. Universitaria s/n, Nuevo Chimbote 02712, Ancash, Peru.

出版信息

Polymers (Basel). 2025 Aug 6;17(15):2146. doi: 10.3390/polym17152146.

Abstract

In light of the environmental impact of disposable products made from petroleum-based plastics, this study focused on developing biodegradable foam trays made from a starch (PS) derived from potato waste and beer malt flour (BMBF). The objective of this study was to evaluate the effect of the concentration of BMBF on the physical and mechanical properties of potato starch-based foam trays prepared by the thermoforming process at temperatures of 150 °C (upper plate) and 145 °C (lower plate) for 5 min and 40 s. The results showed that increasing the BMBF concentration from 0 to 40% reduced the moisture content from 4.68% to 3.42%, increased the thickness from 2.63 cm to 4.77 cm, and decreased the density from 0.28 g.cm to 0.15 g.cm. Meanwhile, the water absorption capacity increased from 38.7% to 69.7%. In terms of mechanical properties, increasing the BMBF concentration in the PS foam tray resulted in a decrease in hardness from 5.61 N to 2.87 N, a decrease in tensile strength from 2.92 MPa to 0.85 MPa, and a decrease in elongation from 1.42% to 0.59%. Meanwhile, fracturability increased from 2.04 mm to 3.68 mm. FTIR analysis revealed interactions between BMBF and PS in the composite foam tray. Thermogravimetric analysis (TGA) showed two thermal events: one between 20.96 °C and 172.89 °C, and another between 189.14 °C and 517.69 °C, with weight losses of 5.53% and 74.23%, leaving an ash residue of 20.24%. Differential calorimetry analysis (DSC) showed a glass transition at 152.88 °C and a melting at 185.94 °C, with an enthalpy of fusion of 74.11 J.g. Higher concentrations of BMBF (>10%) decreased the water resistance, mechanical strength, and flexibility of the PS foam trays. Therefore, a formulation of 90% PS and 10% BMBF was better for producing a foam tray with improved mechanical properties and water resistance, which could be used as a sustainable alternative to conventional single-use plastic.

摘要

鉴于石油基塑料制成的一次性产品对环境的影响,本研究聚焦于开发由马铃薯废料衍生的淀粉(PS)和啤酒麦芽粉(BMBF)制成的可生物降解泡沫托盘。本研究的目的是评估BMBF浓度对在150℃(上板)和145℃(下板)温度下热成型5分钟40秒制备的马铃薯淀粉基泡沫托盘的物理和机械性能的影响。结果表明,将BMBF浓度从0增加到40%,水分含量从4.68%降至3.42%,厚度从2.63厘米增加到4.77厘米,密度从0.28克/立方厘米降至0.15克/立方厘米。同时,吸水能力从38.7%增加到69.7%。在机械性能方面,PS泡沫托盘中BMBF浓度的增加导致硬度从5.61牛降至2.87牛,拉伸强度从2.92兆帕降至0.85兆帕,伸长率从1.42%降至0.59%。同时,易碎性从2.04毫米增加到3.68毫米。傅里叶变换红外光谱(FTIR)分析揭示了复合泡沫托盘中BMBF与PS之间的相互作用。热重分析(TGA)显示两个热事件:一个在20.96℃至172.89℃之间,另一个在189.14℃至517.69℃之间,失重分别为5.53%和74.23%,留下20.24%的灰分残渣。差示量热分析(DSC)显示在152.88℃有玻璃化转变,在185.94℃有熔融,熔融焓为74.11焦/克。较高浓度的BMBF(>10%)降低了PS泡沫托盘的耐水性、机械强度和柔韧性。因此,90%PS和10%BMBF的配方更有利于生产具有改善的机械性能和耐水性的泡沫托盘,可作为传统一次性塑料的可持续替代品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1133/12349056/2db30f041c9a/polymers-17-02146-g001.jpg

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