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微波合成及激光活化的透明质酸/聚丙烯酸酯/罗勒籽人工增雨致冻/吸湿纳米复合材料

Microwave synthesized and laser activated hyaluronic/polyacrylate/basil seed cloud seeding glaciogenic/hygroscopic nanocomposite.

作者信息

Masoomi Sholeh, Doroodmand Mohammad Mahdi, Eshghi Fazlolah

机构信息

Chemistry Department, Shiraz University, Shiraz, 71348-14336, Iran.

出版信息

Sci Rep. 2025 Aug 18;15(1):30264. doi: 10.1038/s41598-025-01456-7.

DOI:10.1038/s41598-025-01456-7
PMID:40825950
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12361579/
Abstract

Cloud seeding is a technique used for weather modification, but the commonly used material, silver iodide, has environmental concerns. In response to this concern, we report a biocompatible hyaluronate/polyacrylate/basil seed nanocomposite was synthesized in this study using microwave irradiation and chemical esterification. A new approach involving polarized CO laser ablation was developed to enhance the nanocomposite's active surface area. The study focused on investigating changes in morphology and surface area during irradiation, which are crucial for effective cloud seeding while minimizing environmental impact. Thermogravimetric analysis showed acceptable water adsorption/absorption properties of up to 98.55%. with this feature, the synthesized nanostructure displayed hygroscopic properties. Also, these amorphous nanocomposites exhibited pseudo-stacking disorder properties in their X-ray diffraction patterns making them a promising cloud seeding agent with glaciogenic properties. In the present study, after investigating nanocomposites, C5 sample with 5 min microwave radiation and one-minute pulse between each radiation, was chosen as the best among the samples. Evaluation in a calibrated cloud seeding chamber revealed the nanocomposite's reliability, producing up to 1.18 (± 0.11) × 10 particles of active cloud seeding compound per gram within a 45-minute timeframe. These results were observed at temperatures between - 14 and - 16 °C with a relative humidity exceeding 90%.

摘要

人工降雨是一种用于人工影响天气的技术,但常用材料碘化银存在环境问题。针对这一问题,本研究利用微波辐射和化学酯化反应合成了一种生物相容性透明质酸盐/聚丙烯酸盐/罗勒籽纳米复合材料。开发了一种涉及偏振CO激光烧蚀的新方法来增加纳米复合材料的活性表面积。该研究重点考察了辐照过程中形态和表面积的变化,这对于有效实施人工降雨同时将环境影响降至最低至关重要。热重分析表明其水吸附/吸收性能良好,高达98.55%。基于这一特性,合成的纳米结构具有吸湿性。此外,这些非晶态纳米复合材料在X射线衍射图谱中表现出假堆积无序特性,使其成为一种具有成冰特性的有前景的人工降雨剂。在本研究中,在对纳米复合材料进行研究后,选择了微波辐射5分钟且每次辐射之间有1分钟脉冲的C5样品作为最佳样品。在校准的人工降雨试验箱中的评估显示了该纳米复合材料的可靠性,在45分钟内每克产生多达1.18(±0.11)×10个活性人工降雨化合物颗粒。这些结果是在-14至-16°C的温度和相对湿度超过90%的条件下观察到的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/dad655c34769/41598_2025_1456_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/13e5844c1263/41598_2025_1456_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/7dbed5a0cb96/41598_2025_1456_Fig2_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/6b95a6e69eba/41598_2025_1456_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/6bb10141f893/41598_2025_1456_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/037785d8f69d/41598_2025_1456_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/dad655c34769/41598_2025_1456_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/13e5844c1263/41598_2025_1456_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/7dbed5a0cb96/41598_2025_1456_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/b96b4981f68b/41598_2025_1456_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/6b95a6e69eba/41598_2025_1456_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/6bb10141f893/41598_2025_1456_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/037785d8f69d/41598_2025_1456_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e8b/12361579/dad655c34769/41598_2025_1456_Fig7_HTML.jpg

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