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响应面法在模拟水溶液中磁性纳米复合材料对贾纳斯绿和番红O的吸附中的应用

Application of response surface methodology for modeling adsorption of janus green and safranin-O on magnetic nanocomposite from aqueous solutions.

作者信息

Ahmad Irfan, Alhadrawi Dilshad A H, Kanabar Bhavesh, Ramachandran T, Saud Haider Radhi, Shankhyan Aman, Karthikeyan A, Thatoi Dhirendra Nath

机构信息

Department of Clinical Laboratory Sciences, College of Applied Medical Sciences, King Khalid University, Abha, Saudi Arabia.

Department of Computer Techniques Engineering, College of Technical Engineering, The Islamic University, Najaf, Iraq.

出版信息

Sci Rep. 2025 Aug 25;15(1):31252. doi: 10.1038/s41598-025-02644-1.

Abstract

The presence of dyes in water bodies has become a significant concern in recent years. In this study, a magnetic nanocomposite synthesized from activated carbon (AC) and FeO nanoparticles (AC/FeO) was employed as an adsorbent to remove janus green (JG) and safranin-O (SO) dyes. The AC/FeO nanocomposite had particle sizes smaller than 100 nm. The specific surface area, pore size, and pore volume average of the AC/FeO nanocomposite were 329.56 m g, 3.67 nm, and 0.289 cm g, respectively. The pH of AC/FeO magnetic nanocomposite was found to be 5.3. Optimal conditions for removal were determined to be a dye concentration of 20 mg L, a sonication time of 18 min, a nanocomposite dosage of 0.023 g, and a pH of 7. The AC/FeO nanocomposite exhibited excellent adsorption performance, achieving removal efficiencies of 95.79% and 97.60% for JG and SO, respectively. Moreover, the magnetic nanocomposite demonstrated good reusability, making it a promising candidate for removing JG and SO dyes from aqueous solutions. The AC/FeO nanocomposite was used to remove JG and SO from different environmental water samples, and the removal efficiency was obtained in the range of 87.65-94.81%. Overall, this study highlights the potential of the AC/FeO magnetic adsorbent, as an effective adsorbent for removing JG and SO dyes from water, which could have significant implications for water treatment and environmental protection.

摘要

近年来,水体中染料的存在已成为一个重大问题。在本研究中,由活性炭(AC)和FeO纳米颗粒合成的磁性纳米复合材料(AC/FeO)被用作吸附剂,以去除姬姆萨绿(JG)和番红O(SO)染料。AC/FeO纳米复合材料的粒径小于100nm。AC/FeO纳米复合材料的比表面积、孔径和平均孔体积分别为329.56 m²/g、3.67nm和0.289 cm³/g。发现AC/FeO磁性纳米复合材料的pH值为5.3。确定去除的最佳条件为染料浓度20mg/L、超声处理时间18分钟、纳米复合材料用量0.023g和pH值7。AC/FeO纳米复合材料表现出优异的吸附性能,对JG和SO的去除效率分别达到95.79%和97.60%。此外,磁性纳米复合材料表现出良好的可重复使用性,使其成为从水溶液中去除JG和SO染料的有前途的候选材料。AC/FeO纳米复合材料用于去除不同环境水样中的JG和SO,去除效率在87.65-94.81%范围内。总体而言,本研究突出了AC/FeO磁性吸附剂作为从水中去除JG和SO染料的有效吸附剂的潜力,这可能对水处理和环境保护具有重要意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e8d/12378200/2d23e23bc00c/41598_2025_2644_Fig1_HTML.jpg

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