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活性粒子系统的场论及其熵产生

Field theories of active particle systems and their entropy production.

作者信息

Pruessner Gunnar, Garcia-Millan Rosalba

机构信息

Department of Mathematics and Centre of Complexity Science, Imperial College London, SW7 2AZ London, United Kingdom.

Department of Mathematics, King's College London, WC2R 2LS London, United Kingdom.

出版信息

Rep Prog Phys. 2025 Sep 22;88(9). doi: 10.1088/1361-6633/adff30.

Abstract

Active particles that translate chemical energy into self-propulsion can maintain a far-from-equilibrium steady state and perform work. The entropy production measures how far from equilibrium such a particle system operates and serves as a proxy for the work performed. Field theory offers a promising route to calculating entropy production, as it allows for many interacting particles to be considered simultaneously. Approximate field theories obtained by coarse-graining or smoothing that draw on additive noise can capture densities and correlations well, but they generally ignore the microscopic particle nature of the constituents, thereby producing spurious results for the entropy production. As an alternative we demonstrate how to use Doi-Peliti field theories, which capture the microscopic dynamics, including reactions and interactions with external and pair potentials. Such field theories are in principle exact, while offering a systematic approximation scheme, in the form of diagrammatics. We demonstrate how to construct them from a Fokker-Planck equation and show how to calculate entropy production of active matter from first principles. This framework is easily extended to include interaction. We use it to derive exact, compact and efficient general expressions for the entropy production for a vast range of interacting conserved particle systems. These expressions are independent of the underlying field theory and can be interpreted as the spatial average of theentropy production. They are readily applicable to numerical and experimental data. In general, the entropy production due to any pair interaction draws at most on the three point, equal time density; and an-point interaction on the(2n-1)-point density. We illustrate the technique in a number of exact, tractable examples, including some with pair-interaction as well as in a system of many interacting Active Brownian Particles.

摘要

能够将化学能转化为自我推进力的活性粒子可以维持远离平衡的稳态并做功。熵产生衡量了这样一个粒子系统偏离平衡的程度,并作为所做功的代理指标。场论为计算熵产生提供了一条很有前景的途径,因为它允许同时考虑许多相互作用的粒子。通过粗粒化或平滑并利用加性噪声得到的近似场论可以很好地捕捉密度和相关性,但它们通常忽略了组成部分的微观粒子性质,从而在熵产生方面产生虚假结果。作为一种替代方法,我们展示了如何使用多伊 - 佩利蒂场论,它能捕捉微观动力学,包括反应以及与外部和对势的相互作用。这样的场论原则上是精确的,同时以图解法的形式提供了一种系统的近似方案。我们展示了如何从福克 - 普朗克方程构建它们,并展示了如何从第一原理计算活性物质的熵产生。这个框架很容易扩展以包括相互作用。我们用它来推导大量相互作用的守恒粒子系统熵产生的精确、紧凑且有效的一般表达式。这些表达式与基础场论无关,可以解释为熵产生的空间平均值。它们很容易应用于数值和实验数据。一般来说,由于任何对相互作用产生的熵产生最多依赖于三点等时密度;而n点相互作用依赖于(2n - 1)点密度。我们在一些精确、易于处理的例子中说明了该技术,包括一些具有对相互作用的例子以及在许多相互作用的活性布朗粒子系统中。

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