He Yunfei, Jiang Yue, Ren Lingwei, Qian Chenyiyi, Zhang Han, Zhong Yuchi, Qu Xuetong, Dou Jibo, Zhang Shuai, Ding Jiafeng, Zhang Hangjun
School of Engineering, Hangzhou Normal University, Hangzhou 310018, China.
Zhejiang Provincial Key Laboratory of Wetland Intelligent Monitoring and Ecological Restoration, Hangzhou 311121, China.
Toxics. 2025 Aug 20;13(8):695. doi: 10.3390/toxics13080695.
Municipal solid waste incineration fly ash (MSWI FA) is recognized as a hazardous solid waste due to its enrichment in toxic heavy metals and high leaching potential. This review systematically summarizes the current understanding of heavy metal occurrence in MSWI FA and associated environmental risks. Solidification and stabilization methods, such as cement-based curing and chemical immobilization, are widely applied due to their cost-effectiveness and operability, though their long-term stability and recovery potential remain limited. Thermal treatment technologies, including sintering, vitrification, thermal separation, and molten salt processes, have shown excellent performance in reducing volume and enhancing the immobilization or recovery of heavy metals. However, these methods are often limited by high energy demands and operational complexity. Recently, emerging technologies such as electrodialysis, bioleaching, and electrokinetic remediation have demonstrated promising capabilities for selective metal recovery under relatively mild conditions. Nevertheless, these novel approaches remain at an early stage of development and have thus far been validated only at the laboratory or pilot scale. Overall, integrating multiple treatment technologies while advancing resource-oriented and low-carbon approaches will be essential for the sustainable management of MSWI FA.
城市固体废弃物焚烧飞灰(MSWI FA)因其富含有毒重金属且具有高浸出潜力而被视为危险固体废弃物。本综述系统总结了目前对MSWI FA中重金属存在情况及相关环境风险的认识。固化和稳定化方法,如水泥基固化和化学固定,因其成本效益和可操作性而被广泛应用,尽管它们的长期稳定性和回收潜力仍然有限。热处理技术,包括烧结、玻璃化、热分离和熔盐工艺,在减少体积以及增强重金属的固定或回收方面表现出优异性能。然而,这些方法往往受到高能源需求和操作复杂性的限制。最近,电渗析、生物浸出和电动修复等新兴技术已展现出在相对温和条件下选择性回收金属的可观能力。尽管如此,这些新方法仍处于发展初期,目前仅在实验室或中试规模得到验证。总体而言,整合多种处理技术并推进资源导向型和低碳方法对于MSWI FA的可持续管理至关重要。