Yang Changhua, Xiao Di, Wang Jun, Liang Tuo
School of Petroleum Engineering, Xi'an Shiyou University, Xi'an 710065, China.
Engineering Research Center for Development and Control of Low-Permeability and Ultra-Low-Permeability Reservoirs in Western China, Ministry of Education, Xi'an 710065, China.
Gels. 2025 Aug 21;11(8):669. doi: 10.3390/gels11080669.
To address the issues of poor thermal stability, inadequate salt tolerance, and environmental risks in conventional gel systems for the development of high-temperature, high-salinity heterogeneous reservoirs, a triple-synergy gel system comprising anionic polyacrylamide (APAM), polyethyleneimine (PEI), and phenolic resin (SMP) was developed in this study. The optimal synthesis parameters-APAM of 180 mg/L, PEI:SMP = 3:1, salinity of 150,000 ppm, and temperature of 110 °C-were determined via response surface methodology, and a time-viscosity model was established. Compared with existing binary systems, the proposed gel exhibited a mass retention rate of 93.48% at 110 °C, a uniform porous structure (pore size of 2-8 μm), and structural stability under high salinity (150,000 ppm). Nuclear magnetic resonance displacement tests showed that the utilization efficiency of crude oil in 0.1-1 μm micropores increased to 21.32%. Parallel dual-core flooding experiments further confirmed the selective plugging capability in heterogeneous systems with a permeability contrast of 10:1: The high-permeability layer (500 mD) achieved a plugging rate of 98.7%, while the recovery factor of the low-permeability layer increased by 13.6%. This gel system provides a green and efficient profile control solution for deep, high-temperature, high-salinity reservoirs.
为了解决常规凝胶体系在高温、高盐非均质性油藏开发中热稳定性差、耐盐性不足和环境风险等问题,本研究开发了一种由阴离子聚丙烯酰胺(APAM)、聚乙烯亚胺(PEI)和酚醛树脂(SMP)组成的三元协同凝胶体系。通过响应面法确定了最佳合成参数——APAM为180 mg/L,PEI:SMP = 3:1,矿化度为150000 ppm,温度为110℃,并建立了时间-粘度模型。与现有的二元体系相比,所制备的凝胶在110℃下的质量保留率为93.48%,具有均匀的多孔结构(孔径为2-8μm),在高盐度(150000 ppm)下具有结构稳定性。核磁共振驱替试验表明,0.1-1μm微孔中原油的利用效率提高到了21.32%。平行双岩心驱油实验进一步证实了该凝胶体系在渗透率级差为10:1的非均质体系中的选择性封堵能力:高渗透层(500 mD)的封堵率达到98.7%,而低渗透层的采收率提高了13.6%。该凝胶体系为深层、高温、高盐油藏提供了一种绿色高效的调剖解决方案。