Dos Santos Valéria S, Nascimento Andreas, Zadeh Saeed Z, Soares Edson José, Dalmaschio Cleocir José
Programa de Pós-Graduação em Engenharia Mecânica, Universidade Federal de Itajubá, Itajubá 37500-903, Brazil.
Labpol/LabPetro - Department of Chemistry, Federal University of Espírito Santo (UFES), Vitória 29075-910, Brazil.
ACS Omega. 2025 Aug 7;10(32):35930-35939. doi: 10.1021/acsomega.5c03075. eCollection 2025 Aug 19.
Diutan gum (DG) is a microbial polysaccharide with great potential for application in activities associated with the deep drilling industry. This study aims to investigate the rheological behavior of diutan gum in aqueous solutions, focusing on its resistance to thermal and saline stresses for potential application in water-based drilling fluids. Thermogravimetric analysis (TGA) was performed to evaluate the thermal stability of the polymer. Two thermal events were observed from TGA: water desorption (approximately 100 °C) and polymer decomposition (230-274 °C, 40% mass loss). The high decomposition onset temperature (230 °C) exceeds typical drilling fluid requirements (<200 °C), confirming excellent thermal stability for high-temperature, high-pressure (HTHP) applications. The rheological behavior in aqueous solutions at different concentrations (0.75-1.75 g/L), salinities (3-90 g/L NaCl), and temperatures (25-80 °C) was studied and analyzed. Accelerated aging, static aging (SA), and dynamic aging (DA) tests (API RP 13B-1) on diutan gum solutions (1.75 g/L) were performed to evaluate salt tolerance (≤180,000 mg/L NaCl), thermal resilience (≤140 °C), and shear resistance (600 rpm) over 16 h, simulating field conditions. Pseudoplastic rheological behavior was observed for most samples, except for the sample subjected to DA at 140 °C and 600 rpm, which exhibited Newtonian behavior. Additionally, the elastic modulus (' > ″) was more significant at low frequencies (0.1-10 Hz), indicating the potential ability of diutan to form more organized lattice structures, as observed under nearly all studied conditions. Rheological results from SA/DA tests confirmed Pseudoplastic behavior under all conditions, demonstrating the stability of diutan gum despite environmental variations. However, its thermomechanical resistance is limited under extreme conditions (140 °C, 600 rpm). The FTIR spectra confirmed the maintenance of the chemical structure of the diutan, which did not suffer from the loss of functional groups. This stability at high salinity and temperature can be attributed to the ability of diutan to form a double helix structure in aqueous media. This conformation drapes water in its interior and protects the main chain and its functional groups from the degradation imposed on the system. Based on its remarkable thermal and saline stability, diutan gum has emerged as a highly effective additive for water-based drilling fluids, improving wellbore stability, cutting suspension, and overall rheological performance under demanding conditions, including deepwater and presalt oil reservoirs.
迪坦胶(DG)是一种微生物多糖,在与深部钻井行业相关的活动中具有巨大的应用潜力。本研究旨在研究迪坦胶在水溶液中的流变行为,重点关注其对热应力和盐应力的耐受性,以便在水基钻井液中潜在应用。进行了热重分析(TGA)以评估聚合物的热稳定性。从TGA中观察到两个热事件:水脱附(约100℃)和聚合物分解(230 - 274℃,质量损失40%)。高分解起始温度(230℃)超过了典型钻井液的要求(<200℃),证实了其在高温高压(HTHP)应用中具有出色的热稳定性。研究并分析了在不同浓度(0.75 - 1.75 g/L)、盐度(3 - 90 g/L NaCl)和温度(25 - 80℃)下的水溶液中的流变行为。对迪坦胶水溶液(1.75 g/L)进行了加速老化、静态老化(SA)和动态老化(DA)测试(API RP 13B - 1),以评估其在16小时内对盐的耐受性(≤180,000 mg/L NaCl)、热恢复能力(≤140℃)和抗剪切能力(600 rpm),模拟现场条件。除了在140℃和600 rpm下进行DA的样品表现出牛顿流体行为外,大多数样品观察到假塑性流变行为。此外,在低频(0.1 - 10 Hz)下弹性模量(' > ″)更为显著,这表明在几乎所有研究条件下,迪坦胶具有形成更有序晶格结构的潜在能力。SA/DA测试的流变学结果证实了在所有条件下的假塑性行为,表明尽管环境变化,迪坦胶仍具有稳定性。然而,在极端条件(140℃,600 rpm)下其热机械耐受性有限。傅里叶变换红外光谱(FTIR)证实了迪坦胶化学结构的维持,其官能团没有损失。在高盐度和高温下的这种稳定性可归因于迪坦胶在水性介质中形成双螺旋结构的能力。这种构象在其内部包裹着水,并保护主链及其官能团免受系统所施加的降解。基于其卓越的热稳定性和盐稳定性,迪坦胶已成为水基钻井液的一种高效添加剂,可在包括深水和盐下油藏等苛刻条件下提高井筒稳定性、岩屑悬浮能力和整体流变性能。