Kwapiński Tomasz, Kurzyna Marcin, Krawiec Mariusz
Institute of Physics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland.
Institute of Computer Science and Mathematics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland.
Materials (Basel). 2025 Aug 15;18(16):3843. doi: 10.3390/ma18163843.
We investigate the electronic properties of atomic chains placed on group-14 two-dimensional materials, Xenes, by analyzing the local electronic properties. Our results show that the hybridization between the chain and the substrate leads to significant modifications in the local density of states at each chain site, including peak splitting, broadening, and asymmetry. These effects are particularly pronounced for plumbene. Owing to the substrate's V-shaped-like density of states, the chains exhibit strong localization effects and significant intensity variations in the electronic energy spectrum. In addition the present analysis reveals the emergence of charge density waves in atomic chains, for which the appearance and stability conditions are identified and provided. The charge density waves are more pronounced and stabilized by a specific electronic spectrum of Xenes, allowing them to penetrate deeper into the chain interior. Our findings contribute to the broader understanding of the interaction between one-dimensional chains and two-dimensional Xene materials, which have significant implications for developing advanced hybrid nanostructures and next generation electronic devices.
我们通过分析局部电子性质来研究置于第14族二维材料(烯类)上的原子链的电子性质。我们的结果表明,链与衬底之间的杂化导致每个链位点处的局部态密度发生显著变化,包括峰分裂、展宽和不对称性。这些效应在铅烯中尤为明显。由于衬底呈V形的态密度,链表现出强烈的局域化效应以及电子能谱中的显著强度变化。此外,本分析揭示了原子链中电荷密度波的出现,并确定并给出了其出现和稳定的条件。电荷密度波通过烯类的特定电子能谱更为显著且稳定,使其能够更深入地渗透到链内部。我们的研究结果有助于更广泛地理解一维链与二维烯类材料之间的相互作用,这对开发先进的混合纳米结构和下一代电子器件具有重要意义。