Wang Jin, Zheng Lulin, Lan Hong, Sun Wenjibin, Chen Zhonglin, Li Bo, Zuo Yujun, Zhang Yiping, Sun Yi, Wen Fangbo
College of Minging, Guizhou University, Guiyang, China.
College of Resources and Environmental Engineering, Guizhou University, Guiyang, China.
PLoS One. 2025 Aug 28;20(8):e0330388. doi: 10.1371/journal.pone.0330388. eCollection 2025.
In order to reveal the change rule of coal pore structure under the peak cluster landform, coal samples were taken from nine different mountain heights based on the vertical variability of the landform, and the pore structure of the coal samples was tested using a combination of high-pressure mercuric pressure method and low-temperature nitrogen adsorption experiments. The results show that compared with the traditional coal reservoir, the pore structure of coal under the peak cluster landform, such as pore content, specific surface area and pore volume, changes with the change of vertical principal stress in a multi-peak state. The variations in the maximum and minimum values of vertical principal stress at each peak level are 1.04, 1.04, and 1.05 times, respectively. In terms of the adsorption pore volume, the differences between the maximum and minimum values are 2.30, 1.60, and 1.53 times, respectively. Notably, the degree of change between the peaks decreases as the peaks progress. Furthermore, with the increase in vertical principal stress, the degree of change in the specific surface area and pore volume of the corresponding adsorption pore between peaks also diminishes. It shows that the role of peak cluster landform conditions on coal pore structure is significant, and the extent of the role decreases with the increase of vertical principal stresses. Additionally, the vertical principal stress predominantly influences the fractal dimension D1, which is represented as pore surface roughness. The capacity of coal samples for gas adsorption is mainly influenced by the roughness of the pore surfaces and the volume of the adsorption pores. In summary, the degree of microcrack formation in the pores of coal samples is influenced to some extent by the vertical elevation difference characteristics of the peak cluster landform, which not only controls the characteristics of the pore structure, but also affects the gas adsorption capacity of the coal samples. These results highlight the influence of vertical principal stress on coal pore closure and structural changes under the peak cluster landform. The results of the study can provide a reference for further research on further gas storage and enrichment laws, and the mine can judge the risk of protrusion for the gas accumulation capacity of coal under the peaked cluster landform, so as to formulate effective gas prevention and control measures in advance.
为揭示峰丛地貌下煤孔隙结构的变化规律,基于地貌的垂向变异性,从九个不同山高采集煤样,并采用高压压汞法和低温氮吸附实验相结合的方法测试煤样的孔隙结构。结果表明,与传统煤储层相比,峰丛地貌下煤的孔隙结构,如孔隙含量、比表面积和孔隙体积,随垂直主应力的变化呈多峰状态变化。各峰级垂直主应力最大值与最小值的变化分别为1.04、1.04和1.05倍。在吸附孔隙体积方面,最大值与最小值的差异分别为2.30、1.60和1.53倍。值得注意的是,峰间变化程度随峰级推进而减小。此外,随着垂直主应力的增加,相应吸附孔隙的比表面积和孔隙体积在峰间的变化程度也减小。这表明峰丛地貌条件对煤孔隙结构的作用显著,且作用程度随垂直主应力的增加而减小。此外,垂直主应力主要影响以孔隙表面粗糙度表示的分形维数D1。煤样的瓦斯吸附能力主要受孔隙表面粗糙度和吸附孔隙体积的影响。综上所述,煤样孔隙中微裂纹的形成程度在一定程度上受峰丛地貌垂向高差特征的影响,其不仅控制孔隙结构特征,还影响煤样的瓦斯吸附能力。这些结果突出了垂直主应力对峰丛地貌下煤孔隙闭合和结构变化的影响。研究结果可为进一步研究瓦斯赋存与富集规律提供参考,矿井可据此判断峰丛地貌下煤瓦斯积聚能力的突出危险性,从而提前制定有效的瓦斯防治措施。