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[液态金属包覆导电纤维的制备与应用]

[Preparation and application of conductive fiber coated with liquid metal].

作者信息

Liu Chengfeng, Tang Jiabo, Li Ming, Zhang Shihao, Zou Yang, Lyu Yonggang

机构信息

State Key Laboratory of New Textile Materials and Advanced Processing, Wuhan Textile University, Wuhan 430200, P. R. China.

School of Resources and Environment, Wuhan Textile University, Wuhan 430200, P. R. China.

出版信息

Sheng Wu Yi Xue Gong Cheng Xue Za Zhi. 2025 Aug 25;42(4):724-732. doi: 10.7507/1001-5515.202507019.

Abstract

Flexible conductive fibers have been widely applied in wearable flexible sensing. However, exposed wearable flexible sensors based on liquid metal (LM) are prone to abrasion and significant conductivity degradation. This study presented a high-sensitivity LM conductive fiber with integration of strain sensing, electrical heating, and thermochromic capabilities, which was fabricated by coating eutectic gallium-indium (EGaIn) onto spandex fibers modified with waterborne polyurethane (WPU), followed by thermal curing to form a protective polyurethane sheath. This fiber, designated as Spandex/WPU/EGaIn/Polyurethane (SWEP), exhibits a four-layer coaxial structure: spandex core, WPU modification layer, LM conductive layer, and polyurethane protective sheath. The SWEP fiber had a diameter of (458.3 ± 10.4) μm, linear density of (2.37 ± 0.15) g/m, and uniform EGaIn coating. The fiber had excellent conductivity with an average value of (3 716.9 ± 594.2) S/m. The strain sensing performance was particularly noteworthy. A 5 cm × 5 cm woven fabric was fabricated using polyester warp yarns and SWEP weft yarns. The fabric exhibited satisfactory moisture permeability [(536.06 ± 33.15) g/(m ·h)] and maintained stable thermochromic performance after repeated heating cycles. This advanced conductive fiber development is expected to significantly promote LM applications in wearable electronics and smart textile systems.

摘要

柔性导电纤维已广泛应用于可穿戴柔性传感领域。然而,基于液态金属(LM)的外露式可穿戴柔性传感器容易受到磨损且导电性会显著下降。本研究提出了一种具有应变传感、电加热和热致变色功能的高灵敏度LM导电纤维,它是通过将共晶镓铟(EGaIn)涂覆在用水性聚氨酯(WPU)改性的氨纶纤维上,然后热固化形成一层保护性聚氨酯护套制成的。这种纤维被命名为氨纶/水性聚氨酯/共晶镓铟/聚氨酯(SWEP),呈现出四层同轴结构:氨纶芯、WPU改性层、LM导电层和聚氨酯保护护套。SWEP纤维的直径为(458.3±10.4)μm,线密度为(2.37±0.15)g/m,EGaIn涂层均匀。该纤维具有优异的导电性,平均值为(3716.9±594.2)S/m。其应变传感性能尤其值得关注。使用聚酯经纱和SWEP纬纱织造了一块5 cm×5 cm的织物。该织物表现出令人满意的透湿性[(536.06±33.15)g/(m·h)],并且在反复加热循环后保持稳定的热致变色性能。这种先进导电纤维的开发有望显著推动LM在可穿戴电子和智能纺织系统中的应用。

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Liquid Metal-Based Soft Microfluidics.液态金属基软微流控技术。
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