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一种具有内部螺旋结构的用于应变不敏感电子器件的液态金属嵌入皮芯纤维。

A Liquid Metal-Embedded Sheath-Core Fiber with Internal Helical Structure for Strain-Insensitive Electronics.

作者信息

Luo Mengying, Wei Wanru, Guo Qiye, Zhong Weibing, Jia Kangyu, Chang Kangqi, Lu Ying, Li Mufang, Wang Dong

机构信息

Key Laboratory of Textile Fiber and Products, Ministry of Education, Wuhan Textile University, Wuhan, 430200, China.

Institute of Technology for Future Industry, Shenzhen Institute of Information Technology, Shenzhen, 518172, China.

出版信息

Adv Sci (Weinh). 2025 Jul 21:e09547. doi: 10.1002/advs.202509547.

Abstract

Stable conductivity is crucial for flexible wearable devices, ensuring reliable signal transmission, sensing accuracy, optimal display performance, and overall device reliability. However, simultaneously achieving high elasticity, superior conductivity, and robust stability remains a formidable challenge. This study presents a novel core-sheath fiber with an internal helical structure as the core layer and an intrinsic elastic material as the sheath layer, which combines the intrinsic elastic material and extensile spiral structure to realize high stretchability, ultra-conductivity, and strain-insensitivity. The hollow fiber with helical channel is fabricated via coaxial wet-spinning technology by adjusting the flow velocity, with an elongation at break of ≈1440%. Subsequent infusion of liquid metal into the channel endows the fiber with outstanding conductivity, reaching 1.94 × 10 S m. Benefiting from the helical structure, the obtained fibers exhibit outstanding strain-insensitivity with a high Q value of 62.5 (resistance variation <1.6%) under 100% strain and show only 30% resistance change even at 600% elongation. The fibers exhibit superior stability against bending, twisting, and compressive deformations. The PU sheath provides excellent waterproof properties, enabling reliable operation in aqueous environments. Moreover, these fibers can be woven into fabrics, exhibiting outstanding performance in joule heaters, near-field communication, and wireless charging applications.

摘要

稳定的导电性对于柔性可穿戴设备至关重要,可确保可靠的信号传输、传感精度、最佳显示性能以及整体设备可靠性。然而,同时实现高弹性、卓越的导电性和强大的稳定性仍然是一项艰巨的挑战。本研究提出了一种新型的核壳纤维,其核心层为内部螺旋结构,鞘层为固有弹性材料,该纤维将固有弹性材料和可拉伸螺旋结构相结合,以实现高拉伸性、超导电性和应变不敏感性。通过同轴湿法纺丝技术,通过调节流速制备出具有螺旋通道的中空纤维,其断裂伸长率约为1440%。随后将液态金属注入通道,赋予纤维出色的导电性,达到1.94×10 S m。得益于螺旋结构,所得纤维表现出出色的应变不敏感性,在100%应变下具有62.5的高Q值(电阻变化<1.6%),即使在600%伸长率下电阻变化也仅为30%。这些纤维在抗弯曲、扭曲和压缩变形方面表现出卓越的稳定性。聚氨酯鞘层具有出色的防水性能,能够在水性环境中可靠运行。此外,这些纤维可以编织成织物,在焦耳加热器、近场通信和无线充电应用中表现出卓越性能。

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