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利用废弃香蕉皮合成铁纳米颗粒及马克西隆蓝5G的声降解

Iron nanoparticle synthesis using waste banana peels and Maxilon Blue 5G sono-degradation.

作者信息

Yakut Şennur Merve

机构信息

Department of Environmental Engineering, Faculty of Engineering and Architecture, Nevsehir Haci Bektas Veli University, Nevsehir, Turkey.

出版信息

Int J Phytoremediation. 2025 Sep 7:1-13. doi: 10.1080/15226514.2025.2554171.

Abstract

The green synthesis method is a significant approach that offers several advantages, including simplicity, rapidity, and cost-effectiveness in the synthesis of nanoparticles. Iron nanoparticles were synthesized in this work using waste banana peel extract as a capping and reducing agent. The produced nanoparticles were then subjected to a number of characterization procedures, such as Raman spectroscopy, X-ray diffractometry (XRD), zeta potential analysis, Fourier transform infrared (FT-IR) spectroscopy, ultraviolet-visible (UV-VIS) absorption spectroscopy, field scanning electron microscopy (FE-SEM), energy dispersive X-ray analysis (EDX), and thermogravimetric analysis (TGA). The effect of the nanoparticles on dye elimination was next investigated separately and with the aid of ultrasound irridation. To ascertain the efficacy of the nanoparticles, their performance was compared with that of the classical Fenton process. The results showed that 99.7% of the dye was removed within 60 min with a 10 mg/L iron concentration, 10 mg/L hydrogen peroxide (HO) concentration, and 53 kHz ultrasound radiation. In FeNPs reuse, 91% efficiency was achieved in the 2nd cycle, 56% in the 3rd cycle and 51.37% in the 4th cycle.

摘要

绿色合成方法是一种重要的方法,具有多种优点,包括在纳米颗粒合成中具有简单、快速和成本效益等特点。在本研究中,使用废弃香蕉皮提取物作为封端剂和还原剂合成了铁纳米颗粒。然后,对所制备的纳米颗粒进行了一系列表征程序,如拉曼光谱、X射线衍射(XRD)、zeta电位分析、傅里叶变换红外(FT-IR)光谱、紫外-可见(UV-VIS)吸收光谱、场发射扫描电子显微镜(FE-SEM)、能量色散X射线分析(EDX)和热重分析(TGA)。接下来分别研究了纳米颗粒对染料去除的影响,并借助超声辐照进行研究。为了确定纳米颗粒的功效,将其性能与经典芬顿工艺的性能进行了比较。结果表明,在铁浓度为10mg/L、过氧化氢(HO)浓度为10mg/L和超声辐射频率为53kHz的条件下,60分钟内可去除99.7%的染料。在铁纳米颗粒的再利用中,第2个循环达到了91%的效率,第3个循环为56%,第4个循环为51.37%。

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