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沉积在纯镍和高温合金基体上的β-NiAl涂层的氧化与腐蚀评估

Oxidation and Corrosion Evaluation of β‑NiAl Coatings Deposited onto Pure Nickel and Superalloy Substrates.

作者信息

Bhatti Jahanzeb, Chandio Ali Dad

机构信息

Advanced Materials & Sustainable Environment Research Group, Department of Metallurgical Engineering, NED University of Engineering & Technology, Karachi 75270, Sindh, Pakistan.

出版信息

ACS Omega. 2025 Aug 20;10(34):38788-38798. doi: 10.1021/acsomega.5c04044. eCollection 2025 Sep 2.

DOI:10.1021/acsomega.5c04044
PMID:40918336
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12409563/
Abstract

Thermal barrier coatings (TBCs) play a crucial role in protecting aeroengine turbine blades in high-temperature environments. An essential component in these multilayer systems is the bond coat, which guarantees the adhesion of the ceramic topcoat and superalloys. This study employs a high-activity pack aluminizing method to form a coating. This was followed by the assessment of corrosion and oxidation behavior of β-NiAl coating formed onto pure nickel and CMSX-4 single-crystal superalloy substrates. In addition, the substrates without coatings were also subjected to both corrosion and oxidation tests. Thus, several characterization techniques are carried out to study the microstructures, phases, corrosion, and oxidation resistance of the substrate materials and their corresponding coatings. Electrochemical tests exhibited a high corrosion rate of pure nickel substrates with and without β-NiAl coatings in comparison with the CMSX-4 superalloy counterpart. Oxidation tests at 1150 °C for 50 h in open air were carried out. The β-NiAl coatings of all substrates showed better oxidation resistance than those of the substrates. In comparison, pure nickel samples exhibited poor oxidation resistance compared to their CMSX-4 counterparts. Therefore, in general, β-NiAl coatings improve oxidation resistance; however, they may compromise corrosion performance, depending on their substrate material.

摘要

热障涂层(TBCs)在保护航空发动机涡轮叶片免受高温环境影响方面发挥着关键作用。这些多层系统中的一个重要组成部分是粘结层,它确保了陶瓷面层与高温合金之间的附着力。本研究采用高活性包埋渗铝法形成涂层。随后对在纯镍和CMSX-4单晶高温合金基体上形成的β-NiAl涂层的腐蚀和氧化行为进行了评估。此外,未涂覆涂层的基体也进行了腐蚀和氧化试验。因此,采用了几种表征技术来研究基体材料及其相应涂层的微观结构、相、腐蚀和抗氧化性能。电化学测试表明,与CMSX-4高温合金相比,有无β-NiAl涂层的纯镍基体的腐蚀速率都很高。在1150℃的空气中进行了50小时的氧化试验。所有基体的β-NiAl涂层都比基体本身表现出更好的抗氧化性能。相比之下,纯镍样品与其CMSX-4对应物相比表现出较差的抗氧化性能。因此,一般来说,β-NiAl涂层提高了抗氧化性能;然而,根据其基体材料的不同,它们可能会损害腐蚀性能。

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