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涂覆在由碳酸钠溶液在ZAM钢上垂直生长的ZnAlMg-LDH转化膜上的环氧涂层的增强腐蚀性能

Enhanced Corrosion Performance of Epoxy Coatings Painted on ZnAlMg-LDH Conversion Film Vertically Grown on ZAM Steels from Sodium Carbonate Solution.

作者信息

Yu Lei, Hu Ji-Ming

机构信息

Department of Chemistry, Zhejiang University, Hangzhou 310058, China.

出版信息

Molecules. 2025 Aug 25;30(17):3491. doi: 10.3390/molecules30173491.

DOI:10.3390/molecules30173491
PMID:40942018
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12430651/
Abstract

Zinc-aluminum-magnesium (ZAM) steel, with its superior corrosion resistance and mechanical properties, is progressively supplanting traditional galvanized steel and zinc-aluminum steel. In this study, a solution containing sodium carbonate-only was employed as the treatment medium to form a vertically grown layered double hydroxide (LDH) pretreatment layer on the surface of ZAM steel via a simple immersion process at 50 °C. The temperature and salt solution not only provide the conditions for the dissolution of metal ions but also facilitate the formation of LDH products. The resulting LDH pretreatment layer exhibits excellent adhesion to the metal surface and enhances the adhesion of the top epoxy coatings. Furthermore, the "LDH/corrosion inhibitor/epoxy" coating system ensures ZAM steel remains rust-free in a 3.5 wt.% NaCl solution for a minimum of 120 days. This innovative approach offers a promising avenue for extending the durability and service life of ZAM steel in corrosive environments.

摘要

锌铝镁（ZAM）钢凭借其卓越的耐腐蚀性和机械性能，正在逐步取代传统的镀锌钢和锌铝钢。在本研究中，仅含碳酸钠的溶液被用作处理介质，通过在50°C下简单的浸泡工艺，在ZAM钢表面形成垂直生长的层状双氢氧化物（LDH）预处理层。温度和盐溶液不仅为金属离子的溶解提供了条件，还促进了LDH产物的形成。所得的LDH预处理层对金属表面具有优异的附着力，并增强了顶部环氧涂层的附着力。此外，“LDH/缓蚀剂/环氧”涂层体系确保ZAM钢在3.5 wt.%的NaCl溶液中至少120天不生锈。这种创新方法为在腐蚀环境中延长ZAM钢的耐久性和使用寿命提供了一条有前景的途径。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4430/12430651/701400420124/molecules-30-03491-g013.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4430/12430651/701400420124/molecules-30-03491-g013.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4430/12430651/decc79c80d42/molecules-30-03491-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4430/12430651/27f86bef636c/molecules-30-03491-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4430/12430651/4d1120b08024/molecules-30-03491-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4430/12430651/7a7b504ebba3/molecules-30-03491-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4430/12430651/c21f770d7366/molecules-30-03491-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4430/12430651/701400420124/molecules-30-03491-g013.jpg

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3
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4
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