• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

作为具有多种应用的超分子主体的有机盐

Organic Salts as Supramolecular Hosts with Various Applications.

作者信息

Singh Abhay Pratap, Baruah Jubaraj B

机构信息

Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, Assam 781 039, India.

出版信息

ACS Omega. 2025 Aug 24;10(35):39334-39349. doi: 10.1021/acsomega.5c05907. eCollection 2025 Sep 9.

DOI:10.1021/acsomega.5c05907
PMID:40949210
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12423800/
Abstract

Brønsted salts are an integral part of everyday activities in various research areas. This article is on hydrogen-bonded assemblies of host-guest complexes of organic salts referred to as ionic cocrystals. Proton transfer from an organic conjugate acid to a base provides salts, which participate in self-assembly with one or more neutral parent components or guests, providing ionic cocrystals. At first sight, such salts appear like the simplest among all other compounds; they have a large scope as medicine, energy materials, and fertilizers in a native form or as ionic cocrystals. The host systems of Brønsted salts have numerous utilities as materials used in diverse sectors and molecular recognition. The ionic cocrystals have the prospect to control bioavailability, degradation, and specific delivery of one or more components. The compositions and types of salt cocrystals are illustrated to explain the different key structural features. The fundamental issue of their utility in the self-recognition of one of the components is analyzed. Their perspectives on their applications in energy, medicine, the environment, and materials are presented.

摘要

布朗斯特盐是各个研究领域日常活动中不可或缺的一部分。本文论述的是被称为离子共晶体的有机盐主客体配合物的氢键组装体。质子从有机共轭酸转移到碱上形成盐，这些盐与一种或多种中性母体成分或客体参与自组装，从而形成离子共晶体。乍一看，这类盐似乎是所有其他化合物中最简单的；它们以天然形式或作为离子共晶体在医药、能源材料和肥料等领域有广泛应用。布朗斯特盐的主体体系作为用于不同领域的材料和分子识别具有多种用途。离子共晶体有望控制一种或多种成分的生物利用度、降解和特异性递送。文中阐述了盐共晶体的组成和类型，以解释不同的关键结构特征。分析了它们在其中一种成分的自识别中发挥作用的基本问题。介绍了它们在能源、医药、环境和材料领域的应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/b952783707a7/ao5c05907_0028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/7c7241ff5dd9/ao5c05907_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/1c24dc4581d8/ao5c05907_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/10b62b9664b8/ao5c05907_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/1f81d15feb82/ao5c05907_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4ebed6e139de/ao5c05907_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/d3c4ec401629/ao5c05907_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/d56254f7516e/ao5c05907_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/5096e81dd7f0/ao5c05907_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/cec36750191d/ao5c05907_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/c28da517810c/ao5c05907_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/ee99a23d1360/ao5c05907_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/9400f5ccc6dc/ao5c05907_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/1ac5a8a5f486/ao5c05907_0013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/5cfb2358f2ef/ao5c05907_0014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4b6e4f3f3e29/ao5c05907_0015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/7339f46d3a79/ao5c05907_0016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/29eb3cd6a6c9/ao5c05907_0017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4bad35d728b3/ao5c05907_0018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/e734ccc1a249/ao5c05907_0019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4dcc755a9e36/ao5c05907_0020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4945b335cbe7/ao5c05907_0021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/5588d81c6573/ao5c05907_0022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4a44a5b151d2/ao5c05907_0023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/6ee90996f86f/ao5c05907_0024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/bd6e919c98ab/ao5c05907_0025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4e174185d194/ao5c05907_0026.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/7173a1393cd0/ao5c05907_0027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/b952783707a7/ao5c05907_0028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/7c7241ff5dd9/ao5c05907_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/1c24dc4581d8/ao5c05907_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/10b62b9664b8/ao5c05907_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/1f81d15feb82/ao5c05907_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4ebed6e139de/ao5c05907_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/d3c4ec401629/ao5c05907_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/d56254f7516e/ao5c05907_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/5096e81dd7f0/ao5c05907_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/cec36750191d/ao5c05907_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/c28da517810c/ao5c05907_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/ee99a23d1360/ao5c05907_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/9400f5ccc6dc/ao5c05907_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/1ac5a8a5f486/ao5c05907_0013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/5cfb2358f2ef/ao5c05907_0014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4b6e4f3f3e29/ao5c05907_0015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/7339f46d3a79/ao5c05907_0016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/29eb3cd6a6c9/ao5c05907_0017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4bad35d728b3/ao5c05907_0018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/e734ccc1a249/ao5c05907_0019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4dcc755a9e36/ao5c05907_0020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4945b335cbe7/ao5c05907_0021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/5588d81c6573/ao5c05907_0022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4a44a5b151d2/ao5c05907_0023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/6ee90996f86f/ao5c05907_0024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/bd6e919c98ab/ao5c05907_0025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/4e174185d194/ao5c05907_0026.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/7173a1393cd0/ao5c05907_0027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bac1/12423800/b952783707a7/ao5c05907_0028.jpg

相似文献

1
Organic Salts as Supramolecular Hosts with Various Applications.作为具有多种应用的超分子主体的有机盐
ACS Omega. 2025 Aug 24;10(35):39334-39349. doi: 10.1021/acsomega.5c05907. eCollection 2025 Sep 9.
2
Prescription of Controlled Substances: Benefits and Risks管制药品的处方：益处与风险
3
Sexual Harassment and Prevention Training性骚扰与预防培训
4
Aspects of Genetic Diversity, Host Specificity and Public Health Significance of Single-Celled Intestinal Parasites Commonly Observed in Humans and Mostly Referred to as 'Non-Pathogenic'.人类常见且大多被称为“非致病性”的单细胞肠道寄生虫的遗传多样性、宿主特异性及公共卫生意义
APMIS. 2025 Sep;133(9):e70036. doi: 10.1111/apm.70036.
5
Short-Term Memory Impairment短期记忆障碍
6
Electrophoresis电泳
7
Effects of Interventions to Improve Access to Financial Services for Micro, Small, and Medium-Sized Enterprises in Low- and Middle-Income Countries: An Evidence and Gap Map.改善低收入和中等收入国家微型、小型和中型企业金融服务可及性的干预措施的效果：证据与差距图
Campbell Syst Rev. 2025 Sep 10;21(3):e70061. doi: 10.1002/cl2.70061. eCollection 2025 Sep.
8
PROTOCOL: Effects of interventions to improve access to financial services for micro-, small- and medium-sized enterprises in low- and middle-income countries: An evidence and gap map.方案：改善低收入和中等收入国家微型、小型和中型企业金融服务获取情况的干预措施的效果：证据与差距图
Campbell Syst Rev. 2023 Jul 5;19(3):e1341. doi: 10.1002/cl2.1341. eCollection 2023 Sep.
9
Management of urinary stones by experts in stone disease (ESD 2025).结石病专家对尿路结石的管理（2025年结石病专家共识）
Arch Ital Urol Androl. 2025 Jun 30;97(2):14085. doi: 10.4081/aiua.2025.14085.
10
Identifying and Addressing Bullying识别与应对霸凌

本文引用的文献

1
Supra-molecular assembly of mebendazolium and di-hydrogen phosphate ions in a new anthelmintic salt.新型驱虫盐中甲苯达唑鎓与磷酸二氢根离子的超分子组装
Acta Crystallogr E Crystallogr Commun. 2025 Feb 4;81(Pt 3):195-199. doi: 10.1107/S2056989025000714. eCollection 2025 Mar 1.
2
Excited-State Proton Transfer Dynamics of Cyanonaphthol in Protic Ionic Liquids: Concerted Effects of Basicity of Anions and Alkyl Carbons in Cations.
J Phys Chem B. 2025 Feb 6;129(5):1648-1661. doi: 10.1021/acs.jpcb.4c07572. Epub 2025 Jan 22.
3
The Elusive Ternary Intermediates of Chiral Phosphoric Acids in Ion Pair Catalysis─Structures, Conformations, and Aggregation.离子对催化中手性磷酸难以捉摸的三元中间体——结构、构象和聚集
J Am Chem Soc. 2025 Jan 22;147(3):2549-2558. doi: 10.1021/jacs.4c14096. Epub 2025 Jan 9.
4
Trimesic Acid as a Building Block for Ternary and Quaternary Salts and Salt Cocrystals.偏苯三酸作为三元和四元盐及盐共晶体的结构单元。
Cryst Growth Des. 2024 Oct 31;24(22):9403-9414. doi: 10.1021/acs.cgd.4c00779. eCollection 2024 Nov 20.
5
Charge-assisted hydrogen bonding in a bicyclic amide cage: an effective approach to anion recognition and catalysis in water.双环酰胺笼中的电荷辅助氢键：一种在水中进行阴离子识别和催化的有效方法。
Chem Sci. 2024 Sep 18;15(39):16040-9. doi: 10.1039/d4sc05236f.
6
Ionic Hydrogen Bond-Assisted Catalytic Construction of Nitrogen Stereogenic Center via Formal Desymmetrization of Remote Diols.离子氢键辅助催化通过远程二醇的形式去对称化构建氮立体中心。
Angew Chem Int Ed Engl. 2024 Jul 29;63(31):e202404979. doi: 10.1002/anie.202404979. Epub 2024 Jun 25.
7
An unusual ionic cocrystal of ponatinib hydrochloride: characterization by single-crystal X-ray diffraction and ultra-high field NMR spectroscopy.一种不同寻常的盐酸普纳替尼离子共晶体：通过单晶X射线衍射和超高场核磁共振光谱进行表征
CrystEngComm. 2024 Jan 30;26(9):1219-1233. doi: 10.1039/d3ce01062g. eCollection 2024 Feb 27.
8
The curious case of proton migration under pressure in the malonic acid and 4,4'-bipyridine cocrystal.丙二酸与4,4'-联吡啶共晶中质子在压力下迁移的奇特现象。
IUCrJ. 2024 Mar 1;11(Pt 2):168-181. doi: 10.1107/S2052252524000344.
9
Perchlorate-Free Energetic Oxidizers Enabled by Ionic Cocrystallization.通过离子共结晶实现的无高氯酸盐含能氧化剂
J Am Chem Soc. 2024 Jan 24;146(3):1771-1775. doi: 10.1021/jacs.3c12023. Epub 2024 Jan 5.
10
Charge-Assisted Ionic Hydrogen-Bonded Organic Frameworks: Designable and Stabilized Multifunctional Materials.电荷辅助离子氢键有机框架：可设计且稳定的多功能材料。
Chemistry. 2024 Mar 20;30(17):e202303580. doi: 10.1002/chem.202303580. Epub 2024 Jan 17.