Melen Rebecca L, Stephan Douglas W
Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Translational Research Hub Maindy Road, Cathays Cardiff Cymru/Wales CF24 4HQ UK
Department of Chemistry, University of Toronto 80 St. George St. Toronto Ontario M5S3H6 Canada
Chem Sci. 2025 Sep 24;16(39):17987-17990. doi: 10.1039/d5sc90195b. eCollection 2025 Oct 8.
This commentary reflects on the remarkably broad impact the concept of "frustrated Lewis pairs" (FLPs) has had over the past 20 years. Since its initial articulation, this concept has found applications across the periodic table and the discipline, leading to new avenues for synthesis and catalysis, building on the 2011 publication (R. C. Neu, E. Otten, A. Lough and D. W. Stephan, , 2011, , 170, https://doi.org/10.1039/C0SC00398K).
这篇评论文章回顾了“受阻路易斯酸碱对”(FLPs)概念在过去20年中所产生的极为广泛的影响。自其最初提出以来,这一概念已在整个元素周期表及相关学科中得到应用,基于2011年发表的论文(R. C. Neu、E. Otten、A. Lough和D. W. Stephan,《化学科学》,2011年,第170页,https://doi.org/10.1039/C0SC00398K),为合成和催化开辟了新途径。