Portelli C
Physiologie. 1977 Jul-Sep;14(3):207-10.
According to the model presented in this paper, the free energy necessary to the synthesis of the ATP molecules is delivered by a unique mechanism. This mechanism consists in the formation of an (Y:X) orbital, which turns with an angle, having the X atom as a pivot point, such that the Y atom is left out from the covalent bond and is replaced by a proton, released from a water molecule. Thus, a new (X:H) orbital is formed. In this first stage, within the newly formed (X:H) orbital the proton is situated at an internuclear distance equal to the length of the hydrogen bond (X...H). Then, the proton moves towards the nucleus of the X atom until it reaches the internuclear distance corresponding to the minimum energy. By the proton displacement, the two electrons of the (X:H) orbital arrive on an excited state level. Then they fall on their corresponding fundamental orbital, releasing two waves of electronic excitation. The two waves of electronic excitation are further transmitted to an acceptor of energy molecule.
根据本文提出的模型,合成ATP分子所需的自由能是通过一种独特的机制传递的。这种机制在于形成一个(Y:X)轨道,该轨道以X原子为支点转动一定角度,使得Y原子从共价键中脱离出来,并被一个从水分子中释放出来的质子所取代。于是,形成了一个新的(X:H)轨道。在这个第一阶段,在新形成的(X:H)轨道内,质子位于等于氢键(X...H)长度的核间距处。然后,质子朝着X原子的原子核移动,直到达到对应于最低能量的核间距。通过质子的位移,(X:H)轨道的两个电子到达激发态能级。然后它们落到各自相应的基态轨道上,释放出两波电子激发。这两波电子激发进一步传递给一个能量分子受体。