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环境样品中芳基磷酸酯残留的鉴定及气相色谱测定

Identification and gas-liquid chromatographic determination of aryl phosphate residues in environmental samples.

作者信息

Lombardo P, Egry I J

出版信息

J Assoc Off Anal Chem. 1979 Jan;62(1):47-51.

PMID:422504
Abstract

Aryl phosphates are widely used as flame retardant plasticizers and hydraulic fluids. Laboratory exposures of rainbow trout to a commercial phosphate hydraulic fluid in a flow-through system resulted in substantial biomagnification. Aryl phosphate residues in fish are extracted and cleaned up by the AOAC method for pesticides in fatty foods, and are detected by phosphorus-selective gas-liquid chromatography. Residues of several aryl phosphate mixtures were detected in fish near industrial sites at concentrations ranging from 0.04 to 1 ppm (edible portion basis).

摘要

芳基磷酸酯被广泛用作阻燃增塑剂和液压油。在流水系统中,将虹鳟鱼置于实验室环境下,使其接触一种商用磷酸酯液压油,结果导致了显著的生物放大作用。鱼体内的芳基磷酸酯残留可通过美国官方分析化学师协会(AOAC)针对高脂肪食品中农药的方法进行提取和净化,并通过磷选择性气液色谱法进行检测。在工业场地附近的鱼类中检测到了几种芳基磷酸酯混合物的残留,浓度范围为0.04至1 ppm(以可食用部分计)。

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Identification and gas-liquid chromatographic determination of aryl phosphate residues in environmental samples.环境样品中芳基磷酸酯残留的鉴定及气相色谱测定
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Bull Environ Contam Toxicol. 1993 Aug;51(2):289-95. doi: 10.1007/BF00198894.
2
Characterization of four commercial flame retardant aryl phosphates.四种商用芳基磷酸酯的特性描述
Bull Environ Contam Toxicol. 1980 Nov;25(5):755-61. doi: 10.1007/BF01985604.
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Toxicity, absorption and elimination of phosphoric acid triesters by killifish and goldfish.食蚊鱼和金鱼对磷酸三酯的毒性、吸收与消除
Bull Environ Contam Toxicol. 1981 Dec;27(6):775-82. doi: 10.1007/BF01611095.
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A national survey of tri(haloalkyl)-, trialkyl-, and triarylphosphates in Canadian drinking water.加拿大饮用水中三(卤代烷基)磷酸盐、三烷基磷酸盐和三芳基磷酸盐的全国性调查。
Bull Environ Contam Toxicol. 1981 Oct;27(4):450-7. doi: 10.1007/BF01611047.
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Identification of fatty acid anilides in adulterated Spanish cooking oils.掺假西班牙食用油中脂肪酸酰苯胺的鉴定
Bull Environ Contam Toxicol. 1982 Aug;29(2):228-34. doi: 10.1007/BF01606155.
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Identification of aryl/alkyl phosphate residues in foods.
Bull Environ Contam Toxicol. 1982 Aug;29(2):221-7. doi: 10.1007/BF01606154.
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Uptake of tri-p-cresyl phosphate in soybean plants.
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Bull Environ Contam Toxicol. 1986 Jul;37(1):41-6. doi: 10.1007/BF01607726.
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