Ueda I, Eyring H
Anesth Analg. 1979 Nov-Dec;58(6):487-91. doi: 10.1213/00000539-197911000-00009.
There appears to be a tendency to convert pH values into "hydrogen ion concentrations" using the antilog of negative pH values. The present communication describes the thermodynamic basis of pH to explain that the above procedure is erroneous and that pH values should be treated as primary variables. Acidity expressed by the hydrogen ion concentrations measured by titrations (base excess or base deficit) has no bearing with the "hydrogen ion concentrations" derived by the antilog of negative pH.
人们似乎倾向于通过取负pH值的反对数将pH值转换为“氢离子浓度”。本通讯描述了pH的热力学基础，以解释上述做法是错误的，pH值应被视为主要变量。通过滴定法测得的氢离子浓度（碱过剩或碱缺乏）所表示的酸度与通过负pH值的反对数得出的“氢离子浓度”无关。
