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C-糖基黄酮类化合物。阿萨伊拉辛的化学性质。

C-glycosylflavonoids. The chemistry of aspalathin.

作者信息

Koeppen B H, Roux D G

出版信息

Biochem J. 1966 Jun;99(3):604-9. doi: 10.1042/bj0990604.

DOI:10.1042/bj0990604
PMID:4290475
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC1265048/
Abstract
  1. The isolation of aspalathin, the principal phenolic constituent in the leaves of Aspalathus linearis, is described and its properties are discussed. 2. The compound has been identified as 3'-C-beta-d-glucopyranosyl-2',3,4,4',6'-pentahydroxydihydrochalcone by the preparation and analysis of various derivatives, by photochemical oxidation to 2,3-dihydroiso-orientin and by nuclear-magnetic-resonance studies.
摘要
  1. 描述了从线叶金雀花叶子中分离出主要酚类成分刺槐素的过程，并讨论了其性质。2. 通过制备和分析各种衍生物、光化学氧化成2,3-二氢异荭草素以及核磁共振研究，该化合物已被鉴定为3'-C-β-D-吡喃葡萄糖基-2',3,4,4',6'-五羟基二氢查耳酮。

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本文引用的文献

1
C-Glycosylflavonoids. The chemistry of orientin and iso-orientin.C-糖基黄酮类化合物。荭草素和异荭草素的化学性质。
Biochem J. 1965 Nov;97(2):444-8. doi: 10.1042/bj0970444.
2
Condensed tannins. 3. Isolation and estimation of (-)-7:3':4':5'-tetrahydroxyflavan-3-ol, (+)-catechin and (+)-gallocatechin from black-wattle-bark extract.缩合单宁。3. 从黑荆树皮提取物中分离并测定（-）-7:3':4':5'-四羟基黄烷-3-醇、（+）-儿茶素和（+）-没食子儿茶素。
Biochem J. 1960 Jan;74(1):44-9. doi: 10.1042/bj0740044.
3
Filter-paper partition chromatography of sugars: 1. General description and application to the qualitative analysis of sugars in apple juice, egg white and foetal blood of sheep. with a note by R. G. Westall.糖类的滤纸分配色谱法：1. 概述及其在苹果汁、蛋清和绵羊胎儿血液中糖类定性分析的应用。附R.G.韦斯托尔的注释
Biochem J. 1948;42(2):238-50. doi: 10.1042/bj0420238.
4
The flavone C-glycosides and flavonol O-glycosides of Aspalathus acuminatus (rooibos tea).尖叶金雀花（路依保斯茶）中的黄酮碳苷和黄酮醇氧苷。
Biochem J. 1962 Jun;83(3):507-11. doi: 10.1042/bj0830507.