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Electron-spin-resonance evidence for interaction of protons with Mo(V) in reduced forms of xanthine oxidase.

作者信息

Bray R C, Knowles P F, Pick F M, Vänngård T

出版信息

Biochem J. 1968 Apr;107(4):601-2. doi: 10.1042/bj1070601.

DOI:10.1042/bj1070601
PMID:4298322
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC1198705/
Abstract
摘要

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Electron-spin-resonance evidence for interaction of protons with Mo(V) in reduced forms of xanthine oxidase.电子自旋共振证据表明,在黄嘌呤氧化酶的还原形式中质子与钼(V)相互作用。
Biochem J. 1968 Apr;107(4):601-2. doi: 10.1042/bj1070601.
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Electron spin resonance of non-haem iron in xanthine oxidase.黄嘌呤氧化酶中非血红素铁的电子自旋共振
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A new non-functional form of milk xanthine oxidase containing stable quinquivalent molybdenum.一种含有稳定五价钼的新型无功能形式的乳黄嘌呤氧化酶。
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Spin-spin interaction between molybdenum and one of the iron-sulphur systems of xanthine oxidase and its relevance to the enzymic mechanism.钼与黄嘌呤氧化酶的铁硫系统之一之间的自旋-自旋相互作用及其与酶促机制的相关性。
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Numbers and exchangeability with water of oxygen-17 atoms coupled to molybdenum (V) in different reduced forms of xanthine oxidase.不同还原形式的黄嘌呤氧化酶中与钼(V)偶联的氧-17原子的数量及与水的交换性
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Spin-spin interaction between molybdenum and one of the iron-sulphur systems of xanthine oxidase and its relevance to the enzymic mechanism.钼与黄嘌呤氧化酶的铁硫系统之一之间的自旋-自旋相互作用及其与酶促机制的相关性。
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"Rapidly appearing" molybdenum electron-paramagnetic-resonance signals from reduced xanthine oxidase.还原型黄嘌呤氧化酶产生的“快速出现”的钼电子顺磁共振信号。
Biochem J. 1969 Oct;114(4):725-34. doi: 10.1042/bj1140725.
8
Comparison of the molybdenum centres of native and desulpho xanthine oxidase. The nature of the cyanide-labile sulphur atom and the nature of the proton-accepting group.天然型和脱硫型黄嘌呤氧化酶钼中心的比较。氰化物敏感硫原子的性质和质子接受基团的性质。
Biochem J. 1978 Dec 1;175(3):887-97. doi: 10.1042/bj1750887.

本文引用的文献

1
DIRECT STUDIES ON THE ELECTRON TRANSFER SEQUENCE IN XANTHINE OXIDASE BY ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. I. TECHNIQUES AND DESCRIPTION OF SPECTRA.通过电子顺磁共振光谱对黄嘌呤氧化酶中电子传递序列的直接研究。I. 光谱技术与描述
J Biol Chem. 1964 Aug;239:2657-66.
2
Improved xanthine oxidase purification.
Biochim Biophys Acta. 1967;146(2):611-3. doi: 10.1016/0005-2744(67)90253-7.
3
Electron spin resonance of xanthine oxidase substituted with molybdenum-95.用钼-95取代的黄嘌呤氧化酶的电子自旋共振
Nature. 1966 Oct 29;212(5061):467-9. doi: 10.1038/212467a0.
4
Molybdenum-thiol complexes as models for molybdenum bound in enzymes.钼-硫醇配合物作为酶中结合钼的模型。
Nature. 1966 Oct 29;212(5061):465-7. doi: 10.1038/212465a0.