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类异戊二烯烷烃姥鲛烷的微生物代谢

Microbial metabolism of the isoprenoid alkane pristane.

作者信息

McKenna E J, Kallio R E

出版信息

Proc Natl Acad Sci U S A. 1971 Jul;68(7):1552-4. doi: 10.1073/pnas.68.7.1552.

DOI:10.1073/pnas.68.7.1552
PMID:4327007
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC389238/
Abstract

The "inert" hydrocarbon pristane (2,6,10,14-tetramethylpentadecane) can be utilized as the sole source of carbon and energy for growth of a coryneform soil isolate. Identification of the metabolites 4,8,12-trimethyltridecanoic acid and alpha-methylglutaric acid indicates that two pathways of fatty acid metabolism operate in this bacterial strain. The widespread use of pristane as a biological marker appears to be predicated on its structural similarity to phytol and its apparent stability, which may be only a reflection of the inability of microorganisms to carry out its anaerobic destruction.

摘要

“惰性”碳氢化合物降植烷(2,6,10,14-四甲基十五烷)可作为棒状土壤分离菌生长的唯一碳源和能源。代谢产物4,8,12-三甲基十三烷酸和α-甲基戊二酸的鉴定表明,该细菌菌株中存在两条脂肪酸代谢途径。降植烷作为一种生物标志物被广泛使用,似乎是基于其与叶绿醇的结构相似性及其明显的稳定性,而这可能仅仅反映了微生物无法对其进行厌氧破坏。

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本文引用的文献

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Isoprenoid Fatty acids isolated from the kerogen matrix of the green river formation (eocene).从绿河组(始新世)干酪根基质中分离出的异戊二烯脂肪酸。
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A major pathway for the mammalian oxidative degradation of phytanic acid.植烷酸哺乳动物氧化降解的主要途径。
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