P1-2-乙酰氨基-2-脱氧-α-D-吡喃葡萄糖基 P2-多萜醇焦磷酸酯的化学合成 - Suppr | 超能文献

Chemical synthesis of P1-2-acetamido-2-deoxy-alpha-D-glucopyranosyl P2-dolichyl pyrophosphate.

作者信息

Warren C D, Jeanloz R W

出版信息

Carbohydr Res. 1974 Oct;37(1):252-60. doi: 10.1016/s0008-6215(00)87080-9.

DOI:10.1016/s0008-6215(00)87080-9

Abstract

摘要

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Chemical synthesis of P1-2-acetamido-2-deoxy-alpha-D-glucopyranosyl P2-dolichyl pyrophosphate.P1-2-乙酰氨基-2-脱氧-α-D-吡喃葡萄糖基 P2-多萜醇焦磷酸酯的化学合成

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The synthesis of a trisaccharide and a tetrasaccharide lipid intermediate. P1-dolichyl P2-[O-beta-D-mannopyranosyl-(1----4)-O-(2-acetamido-2-deoxy- beta-D-glucopyranosyl)-(1----4)-2-acetamido-2-deoxy-alpha-D- glucopyranosyl] diphosphate and P1-dolichyl P2-[O-alpha-D-mannopyranosyl-(1----3)-O-beta-D- mannopyranosyl-(1----4)-O-(2-acetamido-2-deoxy-beta-D-glucopyranosyl)- (1----4)-2-acetamido-2-deoxy-alpha-D-glucopyranosyl] diphosphate.一种三糖和一种四糖脂质中间体的合成。P1-多萜醇P2-[O-β-D-甘露吡喃糖基-(1→4)-O-(2-乙酰氨基-2-脱氧-β-D-葡萄糖吡喃糖基)-(1→4)-2-乙酰氨基-2-脱氧-α-D-葡萄糖吡喃糖基]二磷酸酯和P1-多萜醇P2-[O-α-D-甘露吡喃糖基-(1→3)-O-β-D-甘露吡喃糖基-(1→4)-O-(2-乙酰氨基-2-脱氧-β-D-葡萄糖吡喃糖基)-(1→4)-2-乙酰氨基-2-脱氧-α-D-葡萄糖吡喃糖基]二磷酸酯。

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Synthesis of the tetrasaccharide lipid intermediate P1-dolichyl P2-[O-alpha-D-mannopyranosyl-(1----6)-O-beta-D-mannopyranosyl-(1----4) -O-(2- acetamido-2-deoxy-beta-D-glucopyranosyl)-(1----4)-2-acetamido-2- deoxy-alpha-D-glucopyranosyl] diphosphate.四糖脂质中间体P1-多萜醇P2-[O-α-D-甘露吡喃糖基-(1→6)-O-β-D-甘露吡喃糖基-(1→4)-O-(2-乙酰氨基-2-脱氧-β-D-吡喃葡萄糖基)-(1→4)-2-乙酰氨基-2-脱氧-α-D-吡喃葡萄糖基]二磷酸的合成。

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