11A（43）型肺炎球菌的型特异性物质
The type-specific substance from Pneumococcus type 11A(43).
作者信息
Kennedy D A, Buchanan J G, Baddiley J
出版信息
Biochem J. 1969 Oct;115(1):37-45. doi: 10.1042/bj1150037.
Abstract
- The type-specific substance from Pneumococcus type 11A(43) is a polymer containing d-glucose, d-galactose, glycerol, phosphate and O-acetyl in the approximate molecular proportions 2:2:1:1:2. 2. Removal of the O-acetyl groups with ammonia gave a compound no longer active towards type 11A antiserum. 3. Treatment of S.11A with sodium borohydride, followed by hydrolysis with alkali yielded a phosphorus-free polysaccharide, whose structure was studied by methylation and by degradation with periodate. 4. Examination of S.11A and its de-O-acetyl derivative by periodate oxidation led to the partial structure (XI) for the type-specific substance, which thus has several features in common with S.18.
摘要
- 11A（43）型肺炎球菌的型特异性物质是一种聚合物，其含有d-葡萄糖、d-半乳糖、甘油、磷酸盐和O-乙酰基，分子比例约为2:2:1:1:2。2. 用氨去除O-乙酰基后得到的化合物对11A型抗血清不再有活性。3. 用硼氢化钠处理11A菌株，随后用碱水解，得到一种无磷多糖，其结构通过甲基化和高碘酸盐降解进行研究。4. 通过高碘酸盐氧化对11A菌株及其脱O-乙酰基衍生物进行检测，得出了型特异性物质的部分结构（XI），因此它与18型菌株有几个共同特征。
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