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Dynamics of axial ligation in metalloporphyrins. I. Imidazole exchange in low-spin ferric porphyrins.

作者信息

La Mar G N, Walker F A

出版信息

J Am Chem Soc. 1972 Nov 29;94(24):8607-8. doi: 10.1021/ja00779a068.

DOI:10.1021/ja00779a068
PMID:4638994
Abstract
摘要

相似文献

1
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Axial ligand orientations in a distorted porphyrin macrocycle: synthesis, structure, and properties of low-spin bis(imidazole)iron(III) and iron(II) porphyrinates.扭曲卟啉大环中的轴向配体取向:低自旋双(咪唑)铁(III)和铁(II)卟啉的合成、结构和性质。
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Dynamics of axial ligation in metalloporphyrins. II. Porphyrin "inversion" and halogen exchange in high-spin iron complexes.金属卟啉中轴向配位的动力学。II. 高自旋铁配合物中的卟啉“反转”和卤素交换
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Switching orientation of two axial imidazole ligands between parallel and perpendicular in low-spin Fe(III) and Fe(II) nonplanar porphyrinates.低自旋 Fe(III)和 Fe(II)非平面卟啉中两个轴向咪唑配体的平行和垂直取向的转换。
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Proton NMR study of coordinated imidazoles in low-spin ferric heme complexes. Assignment of single proton histidine resonance in hemoproteins.低自旋铁血红素配合物中配位咪唑的质子核磁共振研究。血红蛋白中单个质子组氨酸共振的归属。
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Imidazole, imidazolate, and hydroxide complexes of (protoporphyrin IX)iron(III) and its dimethyl ester as model systems for ferric hemoproteins: electron paramagnetic resonance and electronic spectral study.(原卟啉IX)铁(III)及其二甲酯的咪唑、咪唑盐和氢氧化物配合物作为高铁血红素蛋白的模型体系:电子顺磁共振和电子光谱研究
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Axial pertubations on the electronic and magnetic properties of ferric porphyrins. II. Solvent effects on the proton NMR spectra of low-spin cyano complexes.铁卟啉电子和磁性性质的轴向微扰。II. 低自旋氰基配合物质子核磁共振谱的溶剂效应
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