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Synthesis of macrolide antibiotics. I. Stereospecific addition of methyllithium and methylmagnesium iodide to methyl alpha-D-xylo-hexopyranosid-4-ulose derivatives. Determination of the configuration at the branching carbon atom by carbon-13 nuclear magnetic resonance spectroscopy.

作者信息

Miljković M, Gligorijević M, Sato T, Miljković D

出版信息

J Org Chem. 1974 May 17;39(10):1379-86. doi: 10.1021/jo00926a012.

DOI:10.1021/jo00926a012
PMID:4833729
Abstract
摘要

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Synthesis of macrolide antibiotics. I. Stereospecific addition of methyllithium and methylmagnesium iodide to methyl alpha-D-xylo-hexopyranosid-4-ulose derivatives. Determination of the configuration at the branching carbon atom by carbon-13 nuclear magnetic resonance spectroscopy.大环内酯类抗生素的合成。I. 甲基锂和甲基碘化镁对α-D-吡喃木糖己糖-4-酮糖衍生物的立体定向加成。通过碳-13核磁共振光谱法测定支链碳原子的构型。
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