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Characterization and synthesis of volatile compounds from the defensive secretions of some "daddy longlets" (Arachnida: Opiliones: Leiobunum spp.).某些“长脚蛛”（蛛形纲：盲蛛目：肥腹蛛属）防御性分泌物中挥发性化合物的表征与合成
Proc Natl Acad Sci U S A. 1977 Feb;74(2):419-22. doi: 10.1073/pnas.74.2.419.

本文引用的文献

1
Defensive secretions of arthropods.节肢动物的防御性分泌物。
Science. 1966 Sep 16;153(3742):1341-50. doi: 10.1126/science.153.3742.1341.

一种“长腿蜘蛛”（斑纹肥蛛）防御性分泌物中的无环酮类

Acyclic ketones in the defensive secretion of a "daddy longlegs" (Leiobunum vittatum).

作者信息

Meinwald J, Kluge A F, Carrel J E, Eisner T

出版信息

Proc Natl Acad Sci U S A. 1971 Jul;68(7):1467-8. doi: 10.1073/pnas.68.7.1467.

DOI:10.1073/pnas.68.7.1467
PMID:5283937
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC389219/
Abstract

The defensive secretion of the "daddy longlegs" Leiobunum vittatum was analyzed and found to contain the acyclic ketones 4-methylheptan-3-one and E-4,6-dimethyl-6-octen-3-one as its major organic components. Although 4-methylheptan-3-one has been found previously as an alarm substance in certain ant genera, the second component, whose structure is confirmed by synthesis, is new.

摘要

对长脚蛛Leiobunum vittatum的防御性分泌物进行了分析，发现其主要有机成分包含无环酮4-甲基庚-3-酮和E-4,6-二甲基-6-辛烯-3-酮。虽然4-甲基庚-3-酮此前已在某些蚁属中作为警戒物质被发现，但经合成确认结构的第二种成分却是新发现的。