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用极谱法在无水体系中研究多环化合物的电化学性质。VII. 致癌烃在二甲基甲酰胺中的极谱氧化

Electrochemical properties of polycyclic compounds studied by the polarographic method in anhydrous systems. VII. Polarographic oxidation of carcinogenic hydrocarbons in dimethylformamide.

作者信息

Podaný V, Benesová M, Bahna L

出版信息

Neoplasma. 1979;26(6):685-9.

PMID:542208
Abstract

The electrooxidation of polycyclic carcinogenic hydrocarbons in dimethylformamide solutions was studied by polarography. The results generally have confirmed that a correlation exists between oxidation potentials and carcinogenic activity of the studied polycyclic aromatic hydrocarbons. The half-wave potentials of the polarographic curves have been found to be directly related to the root xn of the Hückel secular equation for the highest bonding orbital and to the reduction potentials measured in dimethylformamide.

摘要

通过极谱法研究了多环致癌烃在二甲基甲酰胺溶液中的电氧化作用。结果总体上证实了所研究的多环芳烃的氧化电位与致癌活性之间存在相关性。已发现极谱曲线的半波电位与最高成键轨道的休克尔久期方程的根xn以及在二甲基甲酰胺中测得的还原电位直接相关。

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