[牛肉胰岛素双（S-甲氧基羰基硫代）-B链的合成（作者译）]
[Synthesis of the bis(S-methoxycarbonylthio)-B-chain of beef insulin (author's transl)].
作者信息
Nokihara K, Berndt H
出版信息
Hoppe Seylers Z Physiol Chem. 1979 Jun;360(6):773-6.
PMID:572807
Abstract
The bis(S-methoxycarbonylthio)-B-chain of beef insulin was synthesized from B-chain bis(S-sulfonate) and methoxycarbonyl-sulfenylchloride and reacted with thioglycolic acid as well as with cysteine in acidic solution to the corresponding unsymmetrical disulfides in 80% yield.
摘要
牛胰岛素的双（S-甲氧基羰基硫代）-B链由B链双（S-磺酸盐）与甲氧基羰基亚磺酰氯合成，并在酸性溶液中与巯基乙酸以及半胱氨酸反应，以80%的产率生成相应的不对称二硫键。
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