通过将6,8 - 二取代 - 2 - 氧杂双环[3.2.1]辛烷 - 3 - 酮重排为4,5 - 二取代 - 全氢环戊并[b]呋喃 - 2 - 酮来全合成前列腺素 - E2 。 - Suppr | 超能文献

Total synthesis of prostaglandin-E2 by rearrangement of a 6,8-disubstituted-2-oxabicyclo[3.2.1]octan-3-one to a 4,5 disubstituted-perhydrocyclopenta[b]furan-2-one.

作者信息

Newton R F, Reynolds D P, Webb C F, Young S N, Grudzinski Z, Roberts S M

出版信息

J Chem Soc Perkin 1. 1979(11):2789-92.

Abstract

摘要

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