Ferrier J
J Theor Biol. 1984 Feb 21;106(4):449-53. doi: 10.1016/0022-5193(84)90002-x.
A hypothesis concerning the molecular-dynamical basis of osmosis is presented. According to this hypothesis, osmosis results from the attractive force between solute and water molecules, and the exclusion of the solute from the water transport channels of the membrane. Based on this hypothesis, the osmotic process is predicted to involve a large number of short "spurts" of high magnitude force, with a spurt force per unit area of channel of RT/Vs, where R is the gas constant, T is absolute temperature, and Vs is solute molar volume.
提出了一个关于渗透作用分子动力学基础的假说。根据这一假说,渗透作用源于溶质分子与水分子之间的吸引力,以及溶质被排除在膜的水运输通道之外。基于这一假说,预计渗透过程涉及大量短时间的高强度“喷射”力,通道单位面积的喷射力为RT/Vs,其中R为气体常数,T为绝对温度,Vs为溶质摩尔体积。