2,4,5-三甲氧基苯甲酸和3-甲氧基巴豆酸的分解代谢
Catabolism of 2,4,5-trimethyoxybenzoic acid and 3-methoxycrotonic acid.
作者信息
Lee Y L, Sparnins V L, Dagley S
出版信息
Appl Environ Microbiol. 1978 Apr;35(4):817-9. doi: 10.1128/aem.35.4.817-819.1978.
Abstract
4-Methoxygentisic acid was an intermediate formed when Arthrobacter degraded, 2,4,5-trimethoxybenzoic acid. Isolates of Pseudomonas and Arthrobacter from soil grew at the expense of 3-methoxycrotonic acid. Evidence is presented that enzymatic hydration, with elimination of methanol, accounted for replacement of the methoxyl group of 3-methoxycrotonic acid and also of one methoxyl group of 2,4,5-trimethoxybenzoic acid.
摘要
4-甲氧基龙胆酸是节杆菌降解2,4,5-三甲氧基苯甲酸时形成的一种中间体。从土壤中分离出的假单胞菌和节杆菌菌株能够以3-甲氧基巴豆酸为代价生长。有证据表明，酶促水合作用伴随着甲醇的消除，这解释了3-甲氧基巴豆酸的甲氧基以及2,4,5-三甲氧基苯甲酸的一个甲氧基被取代的原因。
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