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针对煤炭燃烧过程中微量元素和碳氢化合物排放的问题。

To the problem of trace elements and hydrocarbons emissions from combustion of coal.

作者信息

Bezacinský M, Pilátová B, Jirele V, Bencko V

出版信息

J Hyg Epidemiol Microbiol Immunol. 1984;28(2):129-38.

PMID:6470477
Abstract

Coal is and at least by the end of this century is likely to remain the major source of energy in Czechoslovakia. Apart from the chronic air pollution problems associated with emissions of oxides of sulfur and flyash a growing attention is now increasingly centered on atmospheric trace elements emitted from coalfired power plants and on emission of hydrocarbons that are invariably detectable in the combustion product condensate. The air pollution emission data presented here are a result of systematic measurements of actual emissions. The measurement included virtually all larger power plants in Czechoslovakia and were carried out between 1975 and 1981. To allow for quantification of the emission data measured trace element mass balance was determined in these measurements. An attempt was also made to compare the relative power industry data obtained in Czechoslovakia with those reported from the USA. A broad spectrum of hydrocarbons found in the condensate of combustion products originating during the coal mass combustion seemed to indicate the presence of both burning and pyrolitic processes, but the mechanism of pyrolysis is as yet unclear. Apart from organics the condensate was found to contain a relatively large amount of fluoride compounds (hundreds of mg X 1(-1) condensate). There is suspicion that this fluorine may occupy an important position among the factors responsible for the ecologic damage caused by emissions from coal-fired power plants.

摘要

煤炭目前是,并且至少到本世纪末很可能仍将是捷克斯洛伐克的主要能源。除了与硫氧化物和飞灰排放相关的长期空气污染问题外,现在人们越来越关注燃煤发电厂排放的大气微量元素以及燃烧产物冷凝物中始终可检测到的碳氢化合物排放。这里给出的空气污染排放数据是对实际排放进行系统测量的结果。这些测量几乎涵盖了捷克斯洛伐克所有较大的发电厂,于1975年至1981年期间进行。为了对排放数据进行量化,在这些测量中确定了痕量元素质量平衡。还尝试将在捷克斯洛伐克获得的电力行业相关数据与美国报告的数据进行比较。在煤块燃烧过程中产生的燃烧产物冷凝物中发现的多种碳氢化合物似乎表明存在燃烧和热解过程,但热解机制尚不清楚。除了有机物外,还发现冷凝物中含有相对大量的氟化物(数百毫克×1(-1)冷凝物)。有人怀疑这种氟在燃煤发电厂排放造成生态破坏的因素中可能占据重要地位。

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