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Structural studies on lipiarmycin. I. Characterization by 1H and 13C NMR spectroscopy and isolation of methyl 2-O-methyl-4-O-homodichloroorsellinate-beta-rhamnoside.

作者信息

Martinelli E, Faniuolo L, Tuan G, Gallo G G, Cavalleri B

出版信息

J Antibiot (Tokyo). 1983 Oct;36(10):1312-22. doi: 10.7164/antibiotics.36.1312.

Abstract

1H and 13C NMR spectral studies of lipiarmycin in CDCl3 and in pyridine-d5 provided evidence for the six partial structures I approximately VI and the two sugar units 1 and 2. Acid methanolysis led to the isolation of methyl 2-O-methyl-4-O-homodichloroorsellinate-beta-rhamnoside, whose structure was determined by spectroscopic methods.

摘要

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Structure and biological activity of lipiarmycin B.
J Antibiot (Tokyo). 1988 Mar;41(3):308-15. doi: 10.7164/antibiotics.41.308.

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