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[紫外线对脂质过氧化荧光产物形成的影响]

[Effect of UV-light on formation of fluorescent products of lipid peroxidation].

作者信息

Konev V V, Popov G A

出版信息

Biofizika. 1978 May-Jun;23(3):456-61.

PMID:667149
Abstract

The rate of fluorescent product formation during the peroxidation of polyunsaturated linolenic acid or egg phosphatidylethanolamine and also during the oxidation of linolenic acid together with a phenylalanine and synthetic phosphatidylethanolamine 1,5--3 times more intensive after previous UV-irradiation of the unsaturated fatty acid. Schiff bases are fluorescent products in amine containing systems which are produced in the reaction of the malonaldehyde with amines. It is possible that fluorochromes produced during the only unsaturated acid oxidation are the result of the radical recombination. Accumulation of the oxidated products determined by TBA-reactive substances does not inevitably correlate with the fluorescent intensity in explored systems.

摘要

在多不饱和亚麻酸或鸡蛋磷脂酰乙醇胺过氧化过程中,以及亚麻酸与苯丙氨酸和合成磷脂酰乙醇胺一起氧化过程中,荧光产物形成速率在不饱和脂肪酸预先紫外线照射后增强1.5至3倍。席夫碱是含胺体系中的荧光产物,由丙二醛与胺反应产生。在仅不饱和酸氧化过程中产生的荧光染料可能是自由基重组的结果。由TBA反应性物质测定的氧化产物积累与所研究体系中的荧光强度并不必然相关。

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