鲁贝霉素A和A1（卡米诺霉素II和III）以及鲁贝霉素B和B1（4-羟基鲍霉素醇A1和A2）的绝对结构。
The absolute structures of rubeomycins A and A1 (carminomycins II and III) and rubeomycins B and B1 (4-hydroxybaumycinols A1 and A2).
作者信息
Ogawa Y, Mori H, Yamada N, Kon K
出版信息
J Antibiot (Tokyo). 1984 Jan;37(1):44-56. doi: 10.7164/antibiotics.37.44.
PMID:6698886
Abstract
The absolute configurations of rubeomycins A and A1 (corresponding to carminomycins II and III) and rubeomycins B and B1 (corresponding to 4-hydroxybaumycinols A1 and A2), except at the C-1" position, were determined by comparison of the optical rotations and other spectral data of rubeomycin derivatives with those of daunomycin and L-(+)-lactic acid.
摘要
除C-1" 位外，通过比较鲁贝霉素衍生物与柔红霉素和L-(+)-乳酸的旋光度及其他光谱数据，确定了鲁贝霉素A和A1（对应于洋红霉素II和III）以及鲁贝霉素B和B1（对应于4-羟基鲍霉素醇A1和A2）的绝对构型。
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