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脂质/水混合物中β-胡萝卜素的角分辨去极化共振拉曼研究

Angle resolved depolarised resonance Raman studies of beta-carotene in lipid/water mixtures.

作者信息

van de Ven M, Kattenberg M, van Ginkel G, Verwer W, Levine Y K

出版信息

Biochem Biophys Res Commun. 1984 May 16;120(3):1060-6. doi: 10.1016/s0006-291x(84)80214-4.

Abstract

The orientational ordering of beta-carotene incorporated in lamellar model membranes above their main phase transitions has been studied by angle resolved depolarised Resonance Raman scattering. The ordering strongly depends on the chemical composition of the lipid bilayers: in di-oleoyl lecithin (DOPC) the carotenoid molecules lie parallel to the bilayer plane, while in di-galactosyl diglyceride ( DGDG ) a bimodal distribution was found with molecules lying both parallel and perpendicular to the membrane phase.

摘要

通过角分辨去偏振共振拉曼散射研究了在层状模型膜主相变温度以上掺入的β-胡萝卜素的取向有序性。这种有序性强烈依赖于脂质双层的化学组成:在二油酰卵磷脂(DOPC)中,类胡萝卜素分子与双层平面平行排列,而在二半乳糖基甘油二酯(DGDG)中,发现了一种双峰分布,分子既平行又垂直于膜相排列。

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