Cook S D, Georgette F S, Skinner H B, Haddad R J
J Biomed Mater Res. 1984 May-Jun;18(5):497-512. doi: 10.1002/jbm.820180504.
A porous metal coating applied to a solid substrate implant has been shown, in vivo, to offer advantages over current polymethylmethacrylate cement fixation in orthopedic devices. These advantages may be lost, however, in devices requiring a sintering heat treatment to apply the coating since these treatments may have a detrimental effect on the substrate material mechanical properties. In addition, more biocompatible interface coating materials have come of interest with recent literature reports of metal ion release. These coatings may be of particular use in porous-coated systems since the surface area of implant in contact with the surrounding tissues is greatly increased. This study investigated the effects that both a porous Ti- 6Al -4V alloy coating and a ULTI carbon coating have on the fatigue properties of a Ti- 6Al -4V alloy substrate system. The fatigue properties of uncoated as-received, uncoated sinter heat treated and notched Ti- 6Al -4V material were also investigated. The results of this study revealed endurance limits for Ti- 6Al -4V alloy tested with a rotating beam system of 617 MN/m2 (uncoated as-received), 624 MN/m2 ( ULTI carbon-coated), 377 MN/m2 ( sinter heat treated), 220 MN/m2 (notched) and 138 MN/m2 (porous-coated). No effects on fatigue properties were observed when testing the material in saline compared with air. The slight increase in fatigue strength for the carbon-coated material is thought to be due to the increase in surface hardness resulting from the formation of titanium carbides on the surface. The low-endurance limit of the porous-coated material is due to both the transition from the as-received equiaxed microstructure to a lamellar microstructure upon sintering and to the notch effect created by the porous coating.
已证明,应用于固体基质植入物的多孔金属涂层在体内比目前骨科器械中使用的聚甲基丙烯酸甲酯骨水泥固定具有优势。然而,在需要进行烧结热处理以施加涂层的器械中,这些优势可能会丧失,因为这些处理可能会对基质材料的机械性能产生不利影响。此外,随着最近有关金属离子释放的文献报道,更具生物相容性的界面涂层材料受到了关注。这些涂层在多孔涂层系统中可能特别有用,因为与周围组织接触的植入物表面积大大增加。本研究调查了多孔Ti-6Al-4V合金涂层和ULTI碳涂层对Ti-6Al-4V合金基质系统疲劳性能的影响。还研究了未涂层的到货状态、未涂层的烧结热处理状态以及带缺口的Ti-6Al-4V材料的疲劳性能。本研究结果表明,使用旋转梁系统测试的Ti-6Al-4V合金的耐力极限分别为617 MN/m2(未涂层到货状态)、624 MN/m2(ULTI碳涂层)、377 MN/m2(烧结热处理)、220 MN/m2(带缺口)和138 MN/m2(多孔涂层)。与在空气中测试相比,在盐水中测试材料时未观察到对疲劳性能的影响。碳涂层材料疲劳强度的轻微增加被认为是由于表面形成碳化钛导致表面硬度增加。多孔涂层材料的低耐力极限是由于烧结时从到货状态的等轴微观结构转变为层状微观结构以及多孔涂层产生的缺口效应。