• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

氟化碳酸根磷灰石红外光谱中的F⁻与CO₃²⁻相互作用

F--CO3(2-)-interaction in IR spectra of fluoridated CO3-apatites.

作者信息

Okazaki M

出版信息

Calcif Tissue Int. 1983;35(1):78-81. doi: 10.1007/BF02405010.

DOI:10.1007/BF02405010
PMID:6839192
Abstract

Spectroscopic properties of fluoridated CO3-apatites were studied by means of infrared (IR) absorption analysis. The peak of the IR band caused by CO32-ions at 875 cm-1 shifted to a lower frequency with the degree of fluoridation. This result suggests that there is a significant interaction between F and CO32-ions in the apatite crystals. The interaction of both these ions is discussed with regard to the solubility behavior of fluoridated CO3- apatites in the acetate buffer solution at pH 4.0 and at 37 degrees C. Solubility of these fluoridated CO3-apatites approached that of fluoridated hydroxyapatites at high fluoride content.

摘要

通过红外（IR）吸收分析研究了氟化碳酸根磷灰石的光谱性质。由碳酸根离子（CO32-）在875 cm-1处引起的红外吸收带的峰值随着氟化程度向较低频率移动。该结果表明在磷灰石晶体中氟离子（F-）和碳酸根离子（CO32-）之间存在显著的相互作用。针对氟化碳酸根磷灰石在pH为4.0且温度为37摄氏度的醋酸盐缓冲溶液中的溶解行为，对这两种离子的相互作用进行了讨论。在高氟含量下，这些氟化碳酸根磷灰石的溶解度接近氟化羟基磷灰石的溶解度。

相似文献

1
F--CO3(2-)-interaction in IR spectra of fluoridated CO3-apatites.氟化碳酸根磷灰石红外光谱中的F⁻与CO₃²⁻相互作用
Calcif Tissue Int. 1983;35(1):78-81. doi: 10.1007/BF02405010.
2
Crystallinity, solubility, and dissolution rate behavior of fluoridated CO3 apatites.氟化碳酸根磷灰石的结晶度、溶解度及溶解速率行为
J Biomed Mater Res. 1982 Nov;16(6):851-60. doi: 10.1002/jbm.820160610.
3
Crystallographic behaviour of fluoridated hydroxyapatites containing Mg2+ and CO3(2-) ions.含Mg2+和CO3(2-)离子的氟化羟基磷灰石的晶体学行为。
Biomaterials. 1991 Nov;12(9):831-5. doi: 10.1016/0142-9612(91)90070-q.
4
Crystallographic morphology of heterogeneous fluoridated carbonate apatites.非均相氟化碳酸磷灰石的晶体形态
J Dent Res. 1993 Sep;72(9):1285-90. doi: 10.1177/00220345930720090501.
5
Carbonate ions in apatites: infrared investigations in the upsilon 4 CO3 domain.磷灰石中的碳酸根离子：在υ4 CO3区域的红外研究
Calcif Tissue Int. 1991 Oct;49(4):269-74. doi: 10.1007/BF02556216.
6
Properties of heterogeneous apatites containing magnesium, fluoride, and carbonate.含镁、氟和碳酸盐的非均相磷灰石的性质
Adv Dent Res. 1996 Nov;10(2):252-9. doi: 10.1177/08959374960100022201.
7
Crystallinity and solubility behavior of iron-containing fluoridated hydroxyapatites.含铁氟化羟基磷灰石的结晶度和溶解性
J Biomed Mater Res. 1986 Sep;20(7):879-86. doi: 10.1002/jbm.820200703.
8
Solubility and crystallinity in relation to fluoride content of fluoridated hydroxyapatites.含氟羟基磷灰石的溶解度和结晶度与氟含量的关系。
J Dent Res. 1981 Apr;60(4):845-9. doi: 10.1177/00220345810600041501.
9
Dissolution rate behavior of fluoridated apatite pellets.
J Dent Res. 1981 Nov;60(11):1907-11. doi: 10.1177/00220345810600111401.
10
Solubility, unit cell dimensions and crystallinity of fluoridated human dental enamel.氟化人牙釉质的溶解度、晶胞尺寸和结晶度。
Arch Oral Biol. 1989;34(12):969-73. doi: 10.1016/0003-9969(89)90054-x.

引用本文的文献

1
Effects of nicomethanol hydrofluoride on dental enamel and synthetic apatites: a role for anti-caries protection.氢氟酸烟醇对牙釉质和合成磷灰石的影响：防龋保护作用
Eur Arch Paediatr Dent. 2017 Dec;18(6):411-418. doi: 10.1007/s40368-017-0314-8. Epub 2017 Nov 4.
2
FT-IR microscopy of endochondral ossification at 20 mu spatial resolution.
Calcif Tissue Int. 1989 Jan;44(1):20-4. doi: 10.1007/BF02556236.
3
Carbonate ions in apatites: infrared investigations in the upsilon 4 CO3 domain.磷灰石中的碳酸根离子：在υ4 CO3区域的红外研究

本文引用的文献

1
The effect of carbonate on the solubility of hydroxylapatite.
Arch Oral Biol. 1963 May-Jun;8:251-63. doi: 10.1016/0003-9969(63)90016-5.
2
Solubility behavior of CO3 apatites in relation to crystallinity.碳酸根磷灰石的溶解性与结晶度的关系
Caries Res. 1981;15(6):477-83. doi: 10.1159/000260555.
3
Solubility and crystallinity in relation to fluoride content of fluoridated hydroxyapatites.含氟羟基磷灰石的溶解度和结晶度与氟含量的关系。
J Dent Res. 1981 Apr;60(4):845-9. doi: 10.1177/00220345810600041501.
Calcif Tissue Int. 1991 Oct;49(4):269-74. doi: 10.1007/BF02556216.
4
Hydroxide and carbonate in rat bone mineral and its synthetic analogues.大鼠骨矿物质及其合成类似物中的氢氧化物和碳酸盐。
Calcif Tissue Res. 1973;13(1):73-82. doi: 10.1007/BF02015398.
5
Relation between apatite solubility and anti-cariogenic effect of fluoride.磷灰石溶解度与氟化物防龋效果之间的关系
Nature. 1973 Jun 15;243(5407):420-1. doi: 10.1038/243420a0.
6
Comparative chemistry of amorphous and apatitic calcium phosphate preparations.非晶态与磷灰石型磷酸钙制剂的比较化学
Calcif Tissue Res. 1972;10(3):171-97. doi: 10.1007/BF02012548.
7
Fluoridated hydroxyapatite solubility and caries formation.含氟羟基磷灰石的溶解度与龋齿形成
Nature. 1974 Jan 4;247(5435):64-5. doi: 10.1038/247064a0.
8
Vibrational spectra of some phosphate salts amorphous to X-ray diffraction.一些对X射线衍射呈非晶态的磷酸盐的振动光谱。
Calcif Tissue Res. 1974 Jun 11;15(1):55-70. doi: 10.1007/BF02059043.
9
Effect of carbonate and biological macromolecules on formation and properties of hydroxyapatite.碳酸盐和生物大分子对羟基磷灰石形成及性能的影响。
Calcif Tissue Res. 1975 Jul 25;18(2):81-90. doi: 10.1007/BF02546228.
10
HPO2-4 content in enamel and artificial carious lesions.牙釉质和人工龋损中HPO2-4的含量
Calcif Tissue Res. 1975 Jul 4;18(1):65-79. doi: 10.1007/BF02546227.