Okazaki K
Shika Rikogaku Zasshi. 1980 Apr;21(54):109-21.
In the previous paper, the author reported 30 wt% Au was more favourable content in Au-Ag-Pd-Cu quaternary dental alloys. In this paper, the experiment was carried out to find suitable Pd and Cu content in 30 wt% Au-Ag-Pd-Cu alloy. Pd and Cu content was changed from 5 wt% to 25 wt% and from 10 wt% to 20 wt% respectively. Ag content was balanced, and no other metals was added. Range of solidification temperature, tensile strength, elongation, hardness, corrosion resistivity and castability were tested. Results were as follows. 1) In these alloys, liquidus points were in the range of 880 degree C approximately 140 degree C, but in the majority of alloys, liquidus points were under 1100 degree C. Range of solidification temperature was more narrow in 20 wt% Cu than other Cu content. 2) The tensile strength and elongation of swaged specimens increased as Pd content increased, but in case of cast specimens, mechanical properties were the highest at 15 approximately 20 wt% Pd. The Vicker's hardness was in the range of 116 to 235. 3) The corrosion test in 0.1% Na2S solution indicated that the corrosion resistance was increased with Pd content and alloys contained more than 20 wt% Pd showed good resistance to corrosion. 4) The castability was affected by the Pd content and much decreased between 15 wt% Pd and 20 wt% Pd, but the castability of these alloys is twice as good as the alloys on the market. From these results, it seemed that the alloys containing 15 approximately 20 wt% Pd and 15 approximately 25 wt% Cu were more favourable composition to 30 wt% Au-Ag-Pd-Cu alloys.
在前一篇论文中,作者报道了在Au-Ag-Pd-Cu四元牙科合金中,30 wt%的金含量更为适宜。在本文中,进行了实验以找出30 wt% Au-Ag-Pd-Cu合金中合适的钯和铜含量。钯和铜的含量分别从5 wt%变化到25 wt%以及从10 wt%变化到20 wt%。银含量保持平衡,且未添加其他金属。测试了凝固温度范围、抗拉强度、伸长率、硬度、耐腐蚀性和铸造性能。结果如下:1)在这些合金中,液相线温度在约880℃至140℃范围内,但大多数合金的液相线温度低于1100℃。含20 wt%铜的合金凝固温度范围比其他铜含量的合金更窄。2)锻造试样的抗拉强度和伸长率随钯含量的增加而提高,但对于铸造试样,机械性能在钯含量为15至20 wt%时最高。维氏硬度在116至235范围内。3)在0.1% Na2S溶液中的腐蚀试验表明,耐腐蚀性随钯含量的增加而提高,含钯量超过20 wt%的合金具有良好的耐腐蚀性。4)铸造性能受钯含量的影响,在钯含量为15 wt%至20 wt%之间大幅下降,但这些合金的铸造性能是市场上合金的两倍。从这些结果来看,含15至20 wt%钯和15至25 wt%铜似乎是30 wt% Au-Ag-Pd-Cu合金更适宜的成分。