Packer J E, Mahood J S, Willson R L, Wolfenden B S
Int J Radiat Biol Relat Stud Phys Chem Med. 1981 Feb;39(2):135-41. doi: 10.1080/09553008114550151.
The trichloromethyl peroxy radical Cl3COO reacts with tryptophan, tryptophanyl-tyrosine and with lysozyme to form products whose overall absorption spectrum is different from those observed following the reaction of hydroxyl, bromide, thiocyanate or azide radicals. Two spectral components have been identified: a minor component attributed to the neutral tryptophanyl radical which can react with ascorbate and intramolecularly with tyrosine residues and a major component which does not undergo either of these reactions and is probably a radical adduct.
三氯甲基过氧自由基Cl3COO与色氨酸、色氨酰酪氨酸以及溶菌酶反应，形成的产物其整体吸收光谱不同于羟基、溴、硫氰酸盐或叠氮自由基反应后所观察到的光谱。已鉴定出两个光谱成分：一个次要成分归因于中性色氨酰自由基，它可与抗坏血酸反应并在分子内与酪氨酸残基反应；另一个主要成分不发生上述任何一种反应，可能是一种自由基加合物。
