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[叶绿素及其类似物的脉冲光电导率]

[Impulse photoconductivity of chlorophyll and its analogs].

作者信息

Chernikov V S

出版信息

Biofizika. 1980 Sep-Oct;25(5):775-80.

PMID:7417561
Abstract

Impute photoconductivity of pyridine solutions of chlorophyll a and pheophytin a in the presence of phenylhydrasin was studied, as well as that of tetraphenylporphin, zinc-tetraphenylporphin, mezoporphyrin, zinc-mezoporphyrin, and palladium-mezoporphyrin in the presence of hydrasin hydrate depending on flash intensity and temperature (20--30 degrees C). The lifetimes of anion-radicals and monoprotonated dianions of the studied pigments were estimated, as well as activation energies of some intermediate stages of photoreduction. From the data obtained the ratio between the constant of the death rate of anion-radicals and the total mobility of negative and positive ion-radical was found.

摘要

研究了在存在苯肼的情况下叶绿素a和脱镁叶绿素a吡啶溶液的光导率,以及在存在水合肼的情况下四苯基卟啉、锌-四苯基卟啉、中卟啉、锌-中卟啉和钯-中卟啉的光导率,该光导率取决于闪光强度和温度(20 - 30摄氏度)。估算了所研究色素的阴离子自由基和单质子化二价阴离子的寿命,以及光还原某些中间阶段的活化能。根据所得数据,得出了阴离子自由基死亡率常数与负离子自由基和正离子自由基总迁移率之间的比率。

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