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链霉素的结构,一种戊二烯大环内酯类抗肿瘤抗生素。I. 碳骨架的结构和官能团的位置。

The structure of lienomycin, a pentaene macrolide antitumor antibiotic. I. The structure of the carbon skeleton and the location of functionalities.

作者信息

Pawlak J, Zieliński J, Golik J, Gumieniak J, Borowski E

出版信息

J Antibiot (Tokyo). 1980 Sep;33(9):989-97. doi: 10.7164/antibiotics.33.989.

Abstract

The structure of a novel type of pentaene macrolide named lienomycin (I) was established by selected chemical transformations of I followed by MS examination of the products. This report provides evidence on the structure of the carbon skeleton of I and on the location of functionalities.

摘要

通过对新型五烯大环内酯类化合物连霉素(I)进行特定的化学转化,随后对产物进行质谱分析,确定了其结构。本报告提供了关于连霉素(I)碳骨架结构及其官能团位置的证据。

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